Publications by authors named "Pimpa Limthongkul"

We present the fabrication of graphene oxide (GO) and manganese dioxide (MnO) composite fibers via wet spinning processes, which entails the effects of MnO micromorphology and mass loading on the extrudability of GO/MnO spinning dope and on the properties of resulted composite fibers. Various sizes of rod and sea-urchin shaped MnO microparticles have been synthesized via hydrothermal reactions with different oxidants and hydrothermal conditions. Both the microparticle morphology and mass loading significantly affect the extrudability of the GO/MnO mixture.

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The Li- and Mn-rich layered oxide cathode material class is a promising cathode material type for high energy density lithium-ion batteries. However, this cathode material type suffers from layer to spinel structural transition during electrochemical cycling, resulting in energy density losses during repeated cycling. Thus, improving structural stability is an essential key for developing this cathode material family.

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Background: Posterior long-segment (LS) fixation, short-segment (SS) fixation, and short segment fixation with intermediate screws (SI) have shown good outcomes for the treatment of thoracolumbar burst fractures. However, limited data compared the biomechanical properties between LS fixation and SI. The purpose of this study was to compare the von Mises stresses on the pedicular screw system and bone between posterior LS fixation, SS fixation, and SI for the treatment of thoracolumbar burst fracture.

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Article Synopsis
  • Layered-layered composite (xLiMnO·(1 -x) LiMO) cathodes are promising for high energy density lithium-ion batteries but face stability issues due to complex phase changes during cycling.
  • The preparation methods greatly influence the structural characteristics and stability of these materials, making it essential to understand their relationship with multiscale structural properties.
  • In this study, 0.5LiMnO·0.5LiCoO composites were created with varying heating and cooling rates, revealing that while these rates don't affect crystal or local atomic structures, they significantly impact the microstructure, which in turn influences electrochemical performance.
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Lithium-rich layered oxide materials, xLi2MnO3·(1 - x)LiMO2 (M = Mn, Fe, Co, Ni, etc.), are a promising candidate for use as cathode materials in the batteries of electric vehicles (EVs). This is due to their high energy density (∼900 W h kg-1), which is larger than those of the currently used commercial cathode materials.

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Article Synopsis
  • Lithium rich layered oxide xLiMnO∙(1-x)LiMO materials are being explored as effective cathode materials for advanced lithium-ion batteries, but their electrochemical behaviors are not well understood.
  • This study investigates how different sizes of LiMnO domains in 0.5LiMnO∙0.5LiCoO materials affect phase separation and lithium ion transport kinetics.
  • Findings show that smaller domain sizes initially enable better lithium ion movement, while larger domain sizes improve ion mobility over time by reducing structural changes and defects.
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Mixtures of cellulose acetate (M.W. ∼3 × 10 g/mol) dissolved in 75% v/v acetic acid in water (17% w/w) and ground anatase titania particles with diameters of 197 ± 75 nm (0%, 5% and 10% w/w) were electrospun at 17 kV with a fiber collection distance and a feed rate of 10 cm and 0.

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Layered-layered composite oxides of the form xLiMnO·(1-x) LiMO (M = Mn, Co, Ni) have received much attention as candidate cathode materials for lithium ion batteries due to their high specific capacity (>250mAh/g) and wide operating voltage range of 2.0-4.8 V.

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An aqueous Li-ion flow cell using suspension-based flow electrodes based on the LiTi2(PO4)3-LiFePO4 couple is demonstrated. Unlike conventional flow batteries, the semi-solid approach utilizes fluid electrodes that are electronically conductive. A model of simultaneous advection and electrochemical transport is developed and used to separate flow-induced losses from those due to underlying side reactions.

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