Cross-Linking Reaction of Bio-Based Epoxy Systems: An Investigation into Cure Kinetics.

The cure kinetics of various epoxy resin mixtures, comprising a bisphenol epoxy, two epoxy modifiers, and two hardening agents derived from cardanol technology, were investigated through differential scanning calorimetry (DSC). The development of these mixtures aimed to achieve epoxy materials with a substantial bio-content up to 50% for potential automotive applications, aligning with the 2019 European Regulation on climate neutrality and CO emission. The Friedman isoconversional method was employed to determine key kinetic parameters, such as activation energy and pre-exponential factor, providing insights into the cross-linking process and the Kamal-Sourour model was used to describe and predict the kinetics of the chemical reactions.