Supercooled water drops impacting superhydrophobic textures.

Understanding the interaction of supercooled metastable water with superhydrophobic surface textures is of fundamental significance for unraveling the mechanisms of icing as well as of practical importance for the rational development of surface treatment strategies to prevent icing. We investigate the problem of supercooled water drops impacting superhydrophobic textures for drop supercooling down to -17 °C and find that increased viscous effects significantly influence all stages of impact dynamics, in particular, the impact and meniscus impalement behavior, with severe implications to water retention by the textures (sticky versus rebounding drop) and possible icing. Viscous effects in water supercooling conditions cause a reduction of drop maximum spreading (∼25% at an impact speed of 3 m/s for a millimetric drop) and can significantly decrease the drop recoil speed when the meniscus partially penetrates into the texture, leading to an increase of the contact time up to a factor of 2 in supercooling conditions compared to room temperature.

On the nanoengineering of superhydrophobic and impalement resistant surface textures below the freezing temperature.

The superhydrophobic behavior of nano- and microtextured surfaces leading to rebound of impacting droplets is of great relevance to nature and technology. It is not clear however, if and under what conditions this behavior is maintained when such surfaces are severely undercooled possibly leading to the formation of frost and icing. Here we elucidate key aspects of this phenomenon and show that the outcome of rebound or impalement on a textured surface is affected by air compression underneath the impacting drop and the time scale allowing this air to escape.