Publications by authors named "Philip K Hopke"

Cigarette filter microplastics are composed of cellulose acetate that does not undergo biological or photo-degradation. These microplastics are readily dispersed and can be found abundantly in water, soil, and air. These fibers possess high absorption capabilities, allowing them to collect and retain pollutants such as toxic elements.

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Advanced receptor models can leverage the information derived from optical and chemical variables as input by a variety of instruments at different time resolutions to extract the source specific absorption Ångström exponent (AAE) from aerosol absorption. The multilinear engine (ME-2), a Positive Matrix Factorization (PMF) solver, serves as a proficient tool for performing such analyses, thereby overcoming the constraints imposed by the assumptions in current optical source apportionment methods such as the Aethalometer approach since the use of a-priori AAE values introduces additional uncertainty into the results of optical methods. Comprehensive PM chemical speciation datasets, and aerosol absorption coefficients (b, λ) at seven wavelengths measured by an Aethalometer (AE33), were used in multi-time source apportionment (MT-PMF).

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Water samples were collected during each of the 2012-2019 Cooperative Science and Monitoring Initiative (CSMI) cruises aboard the U.S. EPA R/V Lake Guardian as part of the Great Lakes Fish Monitoring and Surveillance Program (GLFMSP) lower food web contaminant assessment.

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Article Synopsis
  • The study analyzed the relationship between certain types of particulate matter (PM) and hospitalizations or emergency visits for asthma and COPD in New York before and after implementing stricter automobile emission controls.
  • Using statistical methods, it identified that increases in specific PM sources like spark-ignition emissions and secondary sulfates were linked to higher rates of asthma emergency visits, while diesel emissions had a negative association.
  • After the new emission regulations were put in place, there was a decrease in COPD hospital admissions related to some PM sources, but asthma visits generally increased, highlighting the need for further investigation into these trends.
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Comparing the atmospheric deposition chemistry between above and below the planetary boundary layer (PBL) may help understand the impacts from inter-regional air pollutant transport and local emissions to air pollutant deposition. In this study, we monitored ions, soluble and insoluble potentially toxic elements (PTEs), and dissolved organic nitrogen and carbon at the base (M-base: 551 m asl), middle (M-middle: 2400 m asl), and summit (M-summit: 3077 m asl) on Mount Emei. The annual volume-weighted mean (VWM) concentrations of all measured components were substantially higher at M-base than at M-summit, except for Na, Cl, and NO as Na and Cl at M-summit may be largely from ocean and NO to NO transformation may be faster at M-base.

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Local land-sea breezes play an important role in coastal air quality because they circulate air between coastal/urban and marine areas, potentially causing the accumulation of pollutants. This has been observed for the secondary photochemical pollutant ozone. However, particulate matter (PM) also warrants investigation.

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There is a body of evidence that ultrafine particles (UFP, those with diameters ≤ 100 nm) might have significant impacts on health. Accordingly, identifying sources of UFP is essential to develop abatement policies. This study focuses on urban Europe, and aims at identifying sources and quantifying their contributions to particle number size distribution (PNSD) using receptor modelling (Positive Matrix Factorization, PMF), and evaluating long-term trends of these source contributions using the non-parametric Theil-Sen's method.

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Article Synopsis
  • Ambient PM is a complex pollutant with varying chemical compositions and sources across regions, influenced by local conditions and emissions.
  • Current policies mainly target mass concentrations of PM, neglecting the fact that not all sources pose the same health risks, especially those linked to industries and coal combustion.
  • This study utilized positive matrix factorization to analyze PM sources in South Korea and found that specific sources significantly correlate with emergency department visits, indicating the need for tailored regional policies for effective public health management.
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Substantial effects of photochemical reaction losses of volatile organic compounds (VOCs) on factor profiles can be investigated by comparing the differences between daytime and nighttime dispersion-normalized VOC data resolved profiles. Hourly speciated VOC data measured in Shijiazhuang, China from May to September 2021 were used to conduct study. The mean VOC concentration in the daytime and at nighttime were 32.

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  • A study reviewed the impact of heat and cold waves on mortality in the Middle East, identifying a significant link between heat waves and increased all-cause mortality along with cardiovascular deaths.
  • Meta-analysis results indicated that elderly individuals and men are more vulnerable to heat-related mortality, with relative risks of 1.31 and 1.33, respectively.
  • The findings suggest the need for planning response strategies to heat waves and highlight the importance of future research on specific health conditions and healthcare outcomes.
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Accounting for exposure measurement errors has been recognized as a crucial problem in environmental epidemiology for over two decades. Bayesian hierarchical models offer a coherent probabilistic framework for evaluating associations between environmental exposures and health effects, which take into account exposure measurement errors introduced by uncertainty in the estimated exposure as well as spatial misalignment between the exposure and health outcome data. While two-stage Bayesian analyses are often regarded as a good alternative to fully Bayesian analyses when joint estimation is not feasible, there has been minimal research on how to properly propagate uncertainty from the first-stage exposure model to the second-stage health model, especially in the case of a large number of participant locations along with spatially correlated exposures.

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  • Restricted fetal growth (RFG) is linked to higher perinatal mortality and is associated with gestational exposure to various air pollutants like PM, NO, and PAHs.
  • This study analyzed how air pollution exposure during different trimesters affects inflammatory markers in the placenta, involving a cohort of 263 pregnant women in Rochester, NY.
  • Findings indicate that increased PM exposure in early pregnancy is linked to lower placental IL-6 levels, while higher PAH levels were associated with increased TNF-α levels at different stages, suggesting air pollution can change the placenta's inflammatory response at delivery.
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Changes in energy and environmental policies along with changes in the energy markets of New York State over the past two decades, have spurred interest in evaluating their impacts on emissions from various energy generation sectors. This study focused on quantifying these effects on VOC (volatile organic compounds) emissions and their subsequent impacts on air quality within the New York City (NYC) metropolitan area. NYC is an EPA nonattainment region for ozone (O) and likely is a VOC limited region.

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The effect of cooking aerosol on the human heart was investigated in this study. The heart rate and blood pressure of 33 healthy adults were monitored before, exactly after, and two hours post-exposure (30 minutes, 60 minutes, 90 minutes, and 120 minutes after cooking). One hundred twenty grams of ground beef was fried in sunflower oil for twenty minutes using a gas stove without ventilation.

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The presence of heavy metals and metalloids (metal(loid)s) in the food chain is a global problem, and thus, metal(loid)s are considered to be Potentially Toxic Elements (PTEs). Arsenic (As), lead (Pb), mercury (Hg), and cadmium (Cd) are identified as prominent hazards related to human health risks throughout the food chain. This study aimed to carry out a source attribution for metal(loid)s in shallow topsoil of north-midlands, northwest, and border counties of the Republic of Ireland, followed by an assessment of the potential ecological and human health risks.

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South Korea and China have implemented increasingly stringent mitigation measures to reduce the health risks from PM exposure, jointly conducting a ground-based air quality observation study in Northeast Asia. Dispersion normalized positive matrix factorization (DN-PMF) was used to identify PM sources in Seoul and Beijing and assess the effectiveness of the seasonal management programs (SMPs) through a comparative study. Samples were collected during three periods: January-December 2019, September 2020-May 2021, and July 2021-March 2022.

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  • A study found that low-level air pollution is linked to higher HbA1c levels, a marker for hyperglycemia, in pregnant individuals without diabetes.
  • Researchers analyzed blood samples from 224 pregnant people in Rochester, NY, discovering a U-shaped pattern of HbA1c throughout pregnancy.
  • Increased nitrogen oxide (NO) levels were associated with significant rises in HbA1c, particularly during crucial weeks in the first trimester, suggesting air pollution may negatively impact blood sugar control in low-risk pregnancies.
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China's rapid expansion of civil aviation has led to an increase in pollution-related issues, causing adverse health effects on populations near airports and downwind. Accurately quantifying aviation emissions is essential for effective emission management. Here, we developed a high-resolution aviation emissions inventory for China by employing a bottom-up approach that relied on daily flight schedules.

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Article Synopsis
  • Previous studies found a link between higher levels of specific types of particulate matter (PM) and increased cardiovascular hospitalizations in New York, even though overall PM levels dropped.
  • This study used STEMI patient data from the University of Rochester to analyze the effects of various PM types, particularly organic carbon, on heart attack rates from 2014 to 2019.
  • The results indicated that while certain traffic-related PM levels did not correlate with STEMI rates during the later years, higher secondary organic carbon levels might still be linked to an increased risk of heart attacks, especially when looking at data from the early period of the study.
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Background: Influenza healthcare encounters in adults associated with specific sources of PM is an area of active research.

Objective: Following 2017 legislation requiring reductions in emissions from light-duty vehicles, we hypothesized a reduced rate of influenza healthcare encounters would be associated with concentrations of PM from traffic sources in the early implementation period of this regulation (2017-2019).

Methods: We used the Statewide Planning and Research Cooperative System (SPARCS) to study adult patients hospitalized (N = 5328) or treated in the emergency department (N = 18,247) for influenza in New York State.

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Although most source apportionments of VOCs use mixing ratios, about 23 % of published studies use mass concentrations. Thus, systematically exploring the changes in VOC source apportioned results caused by metric differences is important to assess the differences in key precursor apportionment results given the observed increases in O pollution situation. Different monitoring instruments measured hourly VOC volumetric concentrations in three typical Chinese cities (i.

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Prior studies reported excess rates (ERs) of cardiorespiratory events associated with short-term increases in PM concentrations, despite implementation of pollution-control policies. In 2017, Federal Tier 3 light-duty vehicle regulations began, and to-date there have been no assessments of population health effects of the policy. Using the NYS Statewide Planning and Research Cooperative System (SPARCS) database, we obtained hospitalizations and ED visits with a principal diagnosis of asthma or chronic obstructive pulmonary disease (COPD) for residents living within 15 miles of six urban PM monitoring sites in NYS (2014-2019).

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Article Synopsis
  • Consumed VOCs are volatile organic compounds that react to create ozone and secondary organic aerosols, and this study focused on identifying their sources in Shijiazhuang, China during the summer of 2022.
  • The main contributors to consumed VOCs were found to be petrochemical industries and oxidation processes, which had significantly higher contributions during pollution periods compared to non-pollution periods.
  • The study highlighted that emissions from petrochemical industries primarily transported from the southeast were the significant pathway for VOCs, while other sources like natural gas and mixed sources contributed less to the overall consumed VOCs.
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Sea surface temperature (SST), with its complex and dynamic behavior, is a major driver of ocean-atmosphere interactions. The purpose of this study is to investigate the behavior of SST and its prediction using a chaotic approach. Average mutual information (AMI) and Cao methods were used to reconstruct the phase space.

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