Long-term organic carbon preservation enhanced by iron and manganese.

The balance between degradation and preservation of sedimentary organic carbon (OC) is important for global carbon and oxygen cycles. The relative importance of different mechanisms and environmental conditions contributing to marine sedimentary OC preservation, however, remains unclear. Simple organic molecules can be geopolymerized into recalcitrant forms by means of the Maillard reaction, although reaction kinetics at marine sedimentary temperatures are thought to be slow.

Potential use of engineered nanoparticles in ocean fertilization for large-scale atmospheric carbon dioxide removal.

Artificial ocean fertilization (AOF) aims to safely stimulate phytoplankton growth in the ocean and enhance carbon sequestration. AOF carbon sequestration efficiency appears lower than natural ocean fertilization processes due mainly to the low bioavailability of added nutrients, along with low export rates of AOF-produced biomass to the deep ocean. Here we explore the potential application of engineered nanoparticles (ENPs) to overcome these issues.

Impacts of stratigraphic heterogeneity and release pathway on the transport of bacterial cells in porous media.

In order to manage and control the pathogen release from waste streams of various municipal, industrial, and agricultural pollution sources, it is crucial to investigate the impact of release pathways of such contaminants on their fate and transport in groundwater, especially in respect to natural heterogeneities encountered in aquifers. In this laboratory scale study, we investigate the impacts of different release scenarios of Escherichia coli bacteria, including spatially distributed surface recharge and single-point deep injection, as well as mono-pulse and continuous injection on the transport of Escherichia coli within both single-layered and multilayer aquifers. The results demonstrate earlier arrival of bacteria breakthrough curve (BTC) than conservative solute within a single-layer system with textural and continuum scale heterogeneities, attributed to size exclusion mechanism and preferential flow paths.

The impact of nanoparticle aggregation on their size exclusion during transport in porous media: One- and three-dimensional modelling investigations.

Greater particle mobility in subsurface environments due to larger size, known as size exclusion, has been responsible for colloid-facilitated transport of groundwater contaminants. Although size exclusion is not expected for primary engineered nanoparticles (NP), they can grow in size due to aggregation, thereby undergoing size exclusion. To investigate this hypothesis, an accurate population balance modelling approach and other colloid transport theories, have been incorporated into a three-dimensional transport model, MT3D-USGS.

Significance of Early and Late Stages of Coupled Aggregation and Sedimentation in the Fate of Nanoparticles: Measurement and Modeling.

Despite aggregation's crucial role in controlling the environmental fate of nanoparticles (NP), the extent to which current models can describe the progressive stages of NP aggregation/sedimentation is still unclear. In this paper, 24 model combinations of two population-balance models and various collision frequency and settling velocity models are used to analyze spatiotemporal variations in the size and concentration of hydroxyapatite (HAp) NP. The impact of initial conditions and variability in attachment efficiency, α, with aggregate size are investigated.

Continuum-based models and concepts for the transport of nanoparticles in saturated porous media: A state-of-the-science review.

Environmental applications of nanoparticles (NP) increasingly result in widespread NP distribution within porous media where they are subject to various concurrent transport mechanisms including irreversible deposition, attachment/detachment (equilibrium or kinetic), agglomeration, physical straining, site-blocking, ripening, and size exclusion. Fundamental research in NP transport is typically conducted at small scale, and theoretical mechanistic modeling of particle transport in porous media faces challenges when considering the simultaneous effects of transport mechanisms. Continuum modeling approaches, in contrast, are scalable across various scales ranging from column experiments to aquifer.

Modified MODFLOW-based model for simulating the agglomeration and transport of polymer-modified Fe nanoparticles in saturated porous media.

The solute transport model MODFLOW has become a standard tool in risk assessment and remediation design. However, particle transport models that take into account both particle agglomeration and deposition phenomena are far less developed. The main objective of the present study was to evaluate the feasibility of adapting the standard code MODFLOW/MT3D to simulate the agglomeration and transport of three different types of polymer-modified nanoscale zerovalent iron (NZVI) in one-dimensional (1-D) and two-dimensional (2-D) saturated porous media.