The efficacy of wastewater treatment plant on removal of perfluoroalkyl substances and their impacts on the coastal environment of False Bay, South Africa.

Per- and polyfluoroalkyl substances (PFASs), which have their origins in both industrial processes and consumer products, can be detected at all treatment stages in wastewater treatment plants (WWTPs). Quantifying the emissions of PFAS from WWTPs into the marine environment is crucial because of their potential impacts on receiving aquatic ecosystems. In this study, the levels of five PFAS were measured in both influent and effluent sewage water samples obtained from a municipal WWTP, the discharges of which flow into False Bay, on the Indian Ocean coast of Cape Town, South Africa.

Chemometrics, health and environmental risk assessments of commonly consumed biscuits in Lagos and Ibadan metropolises, Southwestern Nigeria.

The United Nations' Agenda 2030 for sustainable development calls, amongst others, for universal action toward ending malnutrition and ensuring healthy living and well-being for all. So, efforts have intensified to attain the sustainable development goal-2 targets on stunting and wasting in children. Reported herein, therefore, is the quantification of metals in biscuits.

Factors in the decline of the African penguin: Are contaminants of emerging concern (CECs) a potential new age stressor?

The African penguin is currently experiencing a significant decline, with just over 10,000 breeding pairs left. A substantial body of research reflects the impacts of contaminants of emerging concern (CECs) on the marine environment, with wastewater treatment plants reported as one of the main sources of CEC release. In South Africa, CECs were identified contaminating the marine environment and bioaccumulating in several marine species.

Limitations of wastewater treatment plants in removing trace anthropogenic biomarkers and future directions: A review.

This review highlights the limitations faced by conventional wastewater treatment plants (WWTPs) in effectively removing contaminants of emerging concern (CECs), heavy metals (HMs), and Escherichia coli (E. coli). This emphasises the limitations of current treatment methods and advocates for innovative approaches to enhance the removal efficiency.

Iron nanoparticles prepared from South African acid mine drainage for the treatment of methylene blue in wastewater.

In this study, three acid mine drainage (AMD) sources were investigated as potential sources of iron for the synthesis of iron nanoparticles using green tea extract (an environmentally friendly reductant) or sodium borohydride (a chemical reductant). Electrical conductivity (EC), total dissolved solids (TDS), dissolved oxygen (DO), oxidation-reduction potential (ORP), ion chromatography (IC), and inductively coupled plasma-mass spectroscopy (ICP-MS) techniques were used to characterize the AMD, and the most suitable AMD sample was selected based on availability. Additionally, three tea extracts were characterized using ferric-reducing antioxidant power (FRAP) and 2,2-diphenyl-1-picryl-hydrazine-hydrate (DPPH), and the most suitable environmentally friendly reductant was selected based on the highest FRAP (1152 µmol FeII/g) and DPPH (71%) values.

Sustainable gliadin - Metal oxide composites for efficient inactivation of Escherichia coli and remediation of cobalt (II) from water.

Bio-based materials facilitate greener approach to engineering novel materials with multifunctional properties for various applications including water treatment. In this study, we extracted gliadin from wheat gluten using alcoholic solvent. The aggregation limitations of gliadin protein were overcome by functionalisation with metal oxides (MOs) TiO, AgFeO and AgFe-TiO prepared by chemical precipitations.

Contaminants of Emerging Concern (CECs) and Male Reproductive Health: Challenging the Future with a Double-Edged Sword.

Approximately 9% of couples are infertile, with half of these cases relating to male factors. While many cases of male infertility are associated with genetic and lifestyle factors, approximately 30% of cases are still idiopathic. Contaminants of emerging concern (CECs) denote substances identified in the environment for the first time or detected at low concentrations during water quality analysis.

Effects of Film Thickness of ALD-Deposited AlO, ZrO and HfO Nano-Layers on the Corrosion Resistance of Ti(N,O)-Coated Stainless Steel.

The goal of this stydy was to explore the potential of the enhanced corrosion resistance of Ti(N,O) cathodic arc evaporation-coated 304L stainless steel using oxide nano-layers deposited by atomic layer deposition (ALD). In this study, we deposited AlO, ZrO, and HfO nanolayers of two different thicknesses by ALD onto Ti(N,O)-coated 304L stainless steel surfaces. XRD, EDS, SEM, surface profilometry, and voltammetry investigations of the anticorrosion properties of the coated samples are reported.

Fabrication and Characterization of Electrospun Waste Polyethylene Terephthalate Blended with Chitosan: A Potential Single-Use Material.

Textile single-use products are dominantly used for hygiene and personal care, many of which are non-biodegradable and are frequently discarded into sewerage systems, thus causing blockages. Thus, there is a need to move towards water-soluble textiles. This research study focuses on transforming or repurposing biomass material and synthetic reusable waste plastic materials to improve waste.

The burden of emerging contaminants upon an Atlantic Ocean marine protected reserve adjacent to Camps Bay, Cape Town, South Africa.

The presence and levels of fifteen chemicals of emerging concerns, including five perfluorinated compounds (PFCs), two industrial chemicals, seven pharmaceuticals and one personal care product, were evaluated in biota, seawater and sediments obtained from near-shore coastal zone in Camps Bay, Cape Town, South Africa. Eight compounds were found in seawater, and between nine to twelve compounds were quantified in marine invertebrates, sediment and seaweed. Diclofenac was the prevalent pharmaceutical with a maximum concentration of 2.

Synthesis of Stabilized Iron Nanoparticles from Acid Mine Drainage and Rooibos Tea for Application as a Fenton-like Catalyst.

Intensive mining activities generate toxic acid mine drainage (AMD) effluents containing a high concentration of metals, including iron. The chemical synthesis of iron nanoparticles from this waste could lead to further environmental concerns. Therefore, the green synthesis of nanoparticles using plants has gained significant interest because of several benefits, including being eco-friendly.

Antimicrobial and cytotoxic activity of electrosprayed chitosan nanoparticles against endodontic pathogens and Balb/c 3T3 fibroblast cells.

The aims of this study were to synthesize highly positively charged chitosan nanoparticles (Ch-Np) using the electrospraying technique, and to test their antimicrobial activity against endodontic pathogens, and cytotoxicity against fibroblast cells. Ch-Np were synthesized from low molecular weight chitosan (LMW-Ch) using the electrospraying technique, and characterized. The antimicrobial activity was evaluated against Streptococcus mutans, Enterococcus faecalis, and Candida albicans in their planktonic state using a Time-Kill Test performed by using broth micro-dilution technique, and against biofilm biomass using a microtiter plate biofilm assay.

Acylation of Anisole With Benzoyl Chloride Over Rapidly Synthesized Fly Ash-Based HBEA Zeolite.

Stable HBEA zeolite with high surface area and strong acid sites was synthesized from coal fly ash-based silica extract via indirect hydrothermal synthesis. The rapid HBEA hydrothermal crystallization times of 8, 10, and 12 h were achieved through a reduced molar water fraction in the synthesis composition. The HBEA zeolites prepared from fly ash silica extract exhibited well-defined spheroidal-shaped crystal morphology with uniform particle sizes of 192, 190, or 239 nm obtained after 8, 10, or 12 h of synthesis time, respectively.

Isolation and characterization of nanocrystalline cellulose from cocoa pod husk (CPH) biomass wastes.

In this paper, cellulose nanocrystals (CNCs) were isolated from the cellulose extracted from cocoa pod husk waste, followed by characterization using XRD, FT-IR, TGA, SEM and TEM to determine its crystallinity, structural properties, thermal characteristics, morphology and dimensions respectively. The result revealed that the cocoa pod husk amorphous segments containing hemicelluloses and lignin were extensively removed with increasing chemical treatments leading to increased purity, crystallinity index and thermal stability of the extracted materials. The diameter, length and crystallinity index of the CNC isolated from the CPH are 10-60 nm, 41-155 nm and 67.

Pharmaceuticals and Personal Care Products in the Marine Environment Around False Bay, Cape Town, South Africa: Occurrence and Risk-Assessment Study.

Pollution of the marine environment has been increasing as a result of anthropogenic activities. The preservation of marine ecosystems as well as the safety of harvested seafood are nowadays a global concern. In the present study, levels of pharmaceuticals and personal care products were assessed in different environmental compartments in the near-shore marine environment of False Bay, Cape Town, South Africa.

Herbicides in Camps Bay (Cape Town, South Africa), supplemented.

During 2017 the herbicides alachlor, atrazine, butachlor, metolachlor, and simazine were detected in water samples, beach sediments and marine biota collected at Camps Bay, Cape Town, South Africa. During that period, the annual rain catchment record was 77,000 m, whereas the volume of chemically laden sewage discharged via the marine outfall was 693,500 m making the marine sewage outfall by far the most predominant source for these herbicides in the bay. The chemical load in the discharged sewage was not removed by the applied pre-treatment step, which only uses a 3 mm screen to eliminate plastic, paper, rags and other foreign materials.

Removal of Pharmaceutical Residues from Water and Wastewater Using Dielectric Barrier Discharge Methods-A Review.

Persistent pharmaceutical pollutants (PPPs) have been identified as potential endocrine disruptors that mimic growth hormones when consumed at nanogram per litre to microgram per litre concentrations. Their occurrence in potable water remains a great threat to human health. Different conventional technologies developed for their removal from wastewater have failed to achieve complete mineralisation.

Fly Ash-Based Geopolymer Building Materials for Green and Sustainable Development.

This study reports on formulations and conditions for producing fly ash-based geopolymers with a view to showing that the compressive strength required for construction applications can be obtained without the addition of aggregates, sand, and/or cement. It was shown in a series of experiments constituting at least 73% fly ash that a compressive strength of up to 90 MPa can be obtained depending on the curing conditions. While high alkalinity resulted in stronger materials, the results showed about 40% savings in CO emissions without using sand and cement.

PM chemical composition and geographical origin of air masses in Cape Town, South Africa.

PM in the indoor and outdoor environment has been linked in epidemiology studies to the symptoms, hospital admissions and development of numerous health outcomes including death. The study was conducted during April 2017 and April 2018. PM samples were collected over 24 h and every third day.

Anticorrosion Coated Stainless Steel as Durable Support for C-N-TiO Photo Catalyst Layer.

The development of durable photocatalytic supports resistant in harsh environment has become challenging in advanced oxidation processes (AOPs) focusing on water and wastewater remediation. In this study, stainless steel (SS), SS/Ti (N,O) and SS/Cr-N/Cr (N,O) anticorrosion layers on SS meshes were dip-coated with sol gel synthesised C-N-TiO photo catalysts pyrolysed at 350 °C for 105 min, using a heating rate of 50 °C/min under N gas. The supported C-N-TiO films were characterised by scanning electron microscopy (SEM) coupled with energy dispersive spectroscopy (EDS), X-ray diffraction (XRD) and Raman spectroscopy.

Presence and risk assessment of herbicides in the marine environment of Camps Bay (Cape Town, South Africa).

The present study was conducted during a time of drought to assess the concentration of herbicides and their potential for accumulation in marine biota found in the near shore marine environment of an urban setting (Camps Bay, Cape Town, South Africa). The purpose was to establish whether raw sewage containing selected persistent chemicals that are released through a local marine outfall would be sufficiently diluted by the ocean to prevent impact on the near-shore marine environment of the suburb Camps Bay. Samples of seawater, sediment, seaweed, and selected marine organisms present in the near shore environment, such as limpets (Cymbula granatina), mussels (Mytilus galloprovincialis), and sea urchins (Parechinus angulosus), were analysed for five indicator herbicides, namely atrazine, alachlor, simazine, metolachlor, and butachlor, with gas chromatography coupled with a mass spectrometer.

Characterization of electron beam deposited NbO coatings for biomedical applications.

Niobium oxide coatings deposited on TiAlV substrates by electron beam deposition and annealed in air at 600 °C and 800 °C were evaluated for their suitability towards dental, maxillofacial or orthopaedic implant applications. A detailed physico-chemical properties investigation was carried out in order to determine their elemental and phase composition, surface morphology and roughness, mechanical properties, wettability, and corrosion resistance in simulated body fluid solution (pH = 7.4) at room temperature.

Occurrences, levels and risk assessment studies of emerging pollutants (pharmaceuticals, perfluoroalkyl and endocrine disrupting compounds) in fish samples from Kalk Bay harbour, South Africa.

A comprehensive analysis of 15 target chemical compounds (pharmaceuticals and personal care product, perfluoroalkyl compounds and industrial chemicals) were carried out to determine their concentrations in selected commercially exploited, wild caught small and medium sized pelagic fish species and their organs (Thyrsites atun (snoek), Sarda orientalis (bonito), Pachymetopon blochii (panga) and Pterogymnus laniarius (hottentot)) obtained from Kalk Bay harbour, Cape Town. Solid phase extraction (SPE) method based on Oasis HLB cartridges were used to concentrate and clean-up the samples. Liquid chromatography-mass spectrometry analysis of these chemical compounds revealed the simultaneous presence of at least 12 compounds in different parts of the selected fish species in nanogram-per-gram dry weight (ng/g dw) concentrations.

Environmental evaluation and nano-mineralogical study of fresh and unsaturated weathered coal fly ashes.

Coal combustion and the disposal of combustion wastes emit enormous quantities of nano-sized particles that pose significant health concerns on exposure, particularly in unindustrialized countries. Samples of fresh and weathered class F fly ash were analysed through various techniques including X-ray fluorescence (XRF), X-ray diffraction (XRD), focused ion beam scanning electron microscopy (FIB-SEM), field-emission gun scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM) coupled with energy dispersive x-ray spectroscopy (EDS), and Raman Spectroscopy. The imaging techniques showed that the fresh and weathered coal fly ash nanoparticles (CFA-NPs) are mostly spherical shaped.