Color Compounds Removal from Tequila Vinasses Using Silica Gel Adsorbents Functionalized with Thiol Moieties: Equilibrium and Kinetics Studies.

Tequila vinasses are organic wastes generated during ethanol fermentation at elevated temperatures (≥90 °C) and pH ≤ 4.0, making them hazardous to the environment. This paper describes a new, simplified UV-vis spectroscopy-based procedure for monitoring the adsorption of color compounds in tequila vinasses onto silica-based adsorbents, along with an optimized synthesis method to produce the most efficient sol-gel synthesized thiol-functionalized adsorbent.

Spatiotemporal variability of pesticides concentration in honeybees (Apis mellifera) and their honey from western Mexico. Risk assessment for honey consumption.

The study conducted in the state of Colima, western Mexico, aimed to assess the 1) occurrence, 2) temporal variability, 3) spatial variability, and 4) potential risk for honeybees and human consumption of pesticide-contaminated honey. For that purpose, 48 pesticides were determined in bees and their honey during both dry and wet seasons. The research considered two variables: land use categorization (irrigated agriculture, rainfed agriculture, grassland, and forest area) and location (coastal, valley, and mountain).

Assessing the environmental pesticides impact of river sediments from a basin in western Mexico: Spatiotemporal distribution, risk assessment of aquatic invertebrates and pesticides prioritization.

The intensive use of pesticides in Mexican agriculture has contributed significantly to the increase in food production, but at the same time represents potential risk to biota. This situation creates a dilemma between the need to increase food production and the preservation of the environment and human health. Aquatic invertebrates play a vital role in the balance of aquatic ecosystems but are sensitive to pesticides contamination.

Detection of Pharmaceutically Active Compounds in Tap Water Samples by Direct Injection HPLC/MS-MS: A Danger Signal in Deficiency in Residue Management.

To date, there is an increased risk to public health and the environment due to the presence of pharmaceutically active compounds within drinking water supply and distribution networks. Owing to this, a direct injection-HPLC/MS-MS method was developed for the simultaneous determination of 16 active pharmaceutical compounds in tap water samples: amoxicillin, ampicillin, cephalexin, cefotaxime, cefuroxime, ciprofloxacin, clarithromycin, clindamycin, chloramphenicol, cyproterone, erythromycin, flutamide, spironolactone, sulfamethoxazole, tamoxifen, and trimethoprim. Limits of detection (LOD) ranged from 0.

Occurrence and temporal distribution of oxandrolone and meclizine in surface water, sediments, fish muscle and otter feces of the Ayuquila-Armería basin, Mexico.

Aquatic ecosystems worldwide are strongly influenced by the productive activities of a region. These activities can generate pollution by compounds with little-known or unknown characteristics and without regulation. Emerging contaminants are a group of compounds that have worldwide begun to be frequently detected in the environment, raising concern about their possible adverse effects on human and environmental health.

Occurrence, spatio-temporal distribution, and human health risk assessment of pesticides in fish along the Ayuquila-Armería River, Mexico.

Pesticide usage has contributed to increasing food production; it has also caused them to be found in ecosystems inducing adverse effects on biota. Fish are the most abundant and diverse vertebrates in the world and are of great importance both economically and ecologically. Some fishes are indicators of the environmental quality of aquatic ecosystems and provide insight as to how pollutants might influence public health.

Study of feces of neotropical otters (Lontra longicaudis) in the Ayuquila-Armería basin, Mexico as biomonitors of the spatiotemporal distribution of pesticides.

The pesticides used have contributed to increasing food production; it has also caused them to be found in most ecosystems and have negative effects on biota. The neotropical otter (Lontra longicaudis) is vulnerable to pesticide accumulation and is characterized by being elusive, so it is necessary to address the use of indirect techniques that evaluate its populations' state in an efficient, logistically simple, and non-invasive way. This study aimed to determine the concentration of 20 pesticides in neotropical otter feces in the Ayuquila-Armería basin and to describe the spatiotemporal variation of these pesticides.

Gut microbiota from Mexican patients with metabolic syndrome and HIV infection: An inflammatory profile.

Aim: A remarkable increase in metabolic syndrome (MetS) has occurred in HIV-infected subjects. Gut dysbiosis is involved in the pathogenesis of metabolic disorders. Therefore, the aim is to explore the profile of the gut microbiota in Mexican population with HIV infection and MetS.

Seasonal Urinary Levels of Glyphosate in Children From Agricultural Communities.

Background: Glyphosate is one of the most commonly used pesticides in agricultural activities worldwide. For the last 20 years, its use has increased rapidly becoming a public health concern. The IARC classified glyphosate as probably carcinogenic; however, the reported evidence is not enough to establish a statement.

Leaching of Metals from e-Waste: From Its Thermodynamic Analysis and Design to Its Implementation and Optimization.

The aim of this study is to design and develop an efficient leaching process based on a fundamental and theoretical thermodynamic analysis and the optimization of the operation parameters via the response surface methodology (RSM). Using this methodology, the design of a leaching process for the recovery of copper, silver, and lead from highly metal-concentrated fractions of e-waste is presented. Thermodynamic predictions were performed through the construction and analysis of Pourbaix diagrams for the specific conditions of the leaching system.

Urinary concentrations of phthalate metabolites in pregnant women living near Chapala Lake, Jalisco, Mexico.

Phthalates are esters of phthalic acid used in a broad array of consumer products and food contact surfaces. Phthalates are known endocrine disruptors and oxidant stressors, and exposure has been associated with premature birth, asthma, obesity, insulin resistance and endometriosis. Though many industrializing countries are known to manufacture phthalates, few studies have examined exposure to phthalates in this context, let alone in rural communities where phthalate-containing products are widely used.

Copper and Antimony Recovery from Electronic Waste by Hydrometallurgical and Electrochemical Techniques.

A strategy for the efficient recovery of highly pure copper and antimony metals from electronic waste (e-waste) was implemented by the combination of hydrometallurgical and electrochemical processes. The focus is on copper recovery as the main component in the leached solution, whereas the antimony recovery process was established as a purification step in order to achieve a highly pure copper deposit. The strategy includes mechanical methods to reduce the size of the wasted printed circuit boards to enhance the efficiency of antimony and copper lixiviation via ferric chloride in acidic media (0.

Erratum: Sierra-Diaz, E.; Celis-de la Rosa, A.J.; Lozano-Kasten, F.; Trasande, L.; Peregrina-Lucano, A.A.; Sandoval-Pinto, E.; Gonzalez-Chavez, H. Urinary Pesticide Levels in Children and Adolescents Residing in Two Agricultural Communities in Mexico. 2019, , 562.

The authors would like to update some important data in the manuscript. In Table 4, the pesticide means were reported in µg/mL, which is incorrect. The correct units are ng/mL (nanograms/milliliter).

Antitumor Effect of Zwitterions of Imidazolium Derived from -methionine in BALB/c Mice with Lymphoma L5178Y.

Background: In the therapy of cancer, several treatments have been designed using nanomaterials, among which gold nanoparticles (AuNPs) have been featured as a promising antitumoral agent. Our research group has developed the synthesis of gold nanoparticles L-AuNPs and D-AuNPs stabilized with zwitterions of imidazolium (L-1 and D-1) derived from L-methionine and D-methionine. Because the stabilizer agent is chiral, we observed through circular dichroism that AuNPs also present chirality; such chirality as well as the fact that the stabilizing agent contains fragments of methionine and imidazolium that are commonly involved in biological processes, opens up the possibility that this system may have biological compatibility.

Urinary Pesticide Levels in Children and Adolescents Residing in Two Agricultural Communities in Mexico.

The use of pesticides in agricultural activities has increased significantly during the last decades. Several studies have reported the health damage that results from exposure to pesticides. In Mexico, hundreds of communities depend economically on agricultural activities.

From metallic gold to [Au(NHC)] complexes: an easy, one-pot method.

A simple and direct method is described to prepare cationic bis(NHC)-Au(i) complexes containing N-alkyl or N-aryl NHC ligands to generate relevant gold complexes using metallic gold as the starting material.

Systematic Review and Meta-analysis of the Pharmacokinetics of Benznidazole in the Treatment of Chagas Disease.

Chagas disease is a neglected parasitic illness affecting approximately 8 million people, predominantly in Latin America. Benznidazole is the drug of choice for treatment, although its availability has been limited. A paucity of knowledge of the pharmacokinetic properties of this drug has contributed to its limited availability in several jurisdictions.