Revealing the role of phosphoric acid in all-vanadium redox flow batteries with DFT calculations and in situ analysis.

The present work suggests the use of a mixed water-based electrolyte containing sulfuric and phosphoric acid for both negative and positive electrolytes of a vanadium redox flow battery. Computational and experimental investigations reveal insights on the possible interactions between the vanadium ions in all oxidation states and sulphate, bisulphate, dihydrogen phosphate ions and phosphoric acid. In situ cycling experiments and ion-specific electrochemical impedance measurements confirmed a significant lowering of the charge-transfer resistance for the reduction of V(iii) ions and, consequently, an increase of the voltaic efficiency associated with the negative side of the battery.

Determination of the X(3872) meson quantum numbers.

The quantum numbers of the X(3872) meson are determined to be J(PC)=1(++) based on angular correlations in B(+)→X(3872)K(+) decays, where X(3872)→π(+)π(-)J/ψ and J/ψ→μ(+)μ(-). The data correspond to 1.0 fb(-1) of pp collisions collected by the LHCb detector.

First observation of CP violation in the decays of B(s)0 mesons.

Using pp collision data corresponding to an integrated luminosity of 1.0 fb(-1) and collected by LHCb in 2011 at a center-of-mass energy of 7 TeV, we report the measurement of direct CP violation in B(s)(0)→K(-)π(+) decays, A(CP)(B(s)(0)→K(-)π(+)=0.27±0.

First measurement of the CP-violating phase in Bs(0) → ϕϕ decays.

A first flavor-tagged measurement of the time-dependent CP-violating asymmetry in B(s)(0) → ϕϕ decays is presented. In this decay channel, the CP-violating weak phase arises due to CP violation in the interference between B(s)(0)-B(s)(0) mixing and the b → sss gluonic penguin decay amplitude. Using a sample of pp collision data corresponding to an integrated luminosity of 1.

Search for rare B(0)((s))→μ(+)μ(-)μ(+)μ(-) decays.

A search for the decays B(0)((s))→μ(+)μ(-)μ(+)μ(-) and B(0)→μ(+)μ(-)μ(+)μ(-) is performed using data, corresponding to an integrated luminosity of 1.0 fb(-1), collected with the LHCb detector in 2011. The number of candidates observed is consistent with the expected background and, assuming phase-space models of the decays, limits on the branching fractions are set: B(B(s)(0)→μ(+)μ(-)μ(+)μ(-))<1.

Measurement of the Λ(b)(0), Ξ (b)(-), and Ω(b((-) Baryon masses.

Bottom baryons decaying to a J/ψ meson and a hyperon are reconstructed using 1.0 fb(-1) of data collected in 2011 with the LHCb detector. Significant Λ(b)(0) → J/ψΛ, Ξ(b((-) → J/ψΞ(-) and Ω(b)(-) → J/ψΩ(-) signals are observed and the corresponding masses are measured to be M(Λ(b)(0))=5619.

First observation of the decay Bs2*(5840)(0)→B*+ K- and studies of excited Bs(0) mesons.

The properties of the orbitally excited (L=1) Bs(0) states are studied by using 1.0  fb(-1) of pp collisions at sqrt[s]=7  TeV collected with the LHCb detector. The first observation of the Bs2*(5840)(0) meson decaying to B*+ K- is reported, and the corresponding branching fraction measured relative to the B+ K- decay mode.

Observation of D0-D0 oscillations.

We report a measurement of the time-dependent ratio of D(0) → K(+) π- to D(0) → K(-) π(+) decay rates in D(*+)-tagged events using 1.0 fb(-1) of integrated luminosity recorded by the LHCb experiment. We measure the mixing parameters x('2) = (-0.

First evidence for the decay B(s)(0)→μ+ μ-.

A search for the rare decays B(s)(0)→μ+ μ- and B(0)→μ+ μ- is performed with data collected in 2011 and 2012 with the LHCb experiment at the Large Hadron Collider. The data samples comprise 1.1  fb(-1) of proton-proton collisions at sqrt[s]=8  TeV and 1.

Measurement of the CP asymmetry in B(0)→K(*0)μ(+)μ(-) decays.

A measurement of the CP asymmetry in B(0)→K(*0)μ(+)μ(-) decays is presented, based on 1.0 fb(-1) of pp collision data recorded by the LHCb experiment during 2011. The measurement is performed in six bins of invariant mass squared of the μ(+)μ(-) pair, excluding the J/ψ and ψ(2S) resonance regions.

Measurements of B(c)+ production and mass with the B(c)+ → J/ψπ+ decay.

Measurements of B(c)(+) production and mass are performed with the decay mode B(c)(+)→J/ψπ(+) using 0.37 fb(-1) of data collected in pp collisions at √[s]=7 TeV by the LHCb experiment. The ratio of the production cross section times branching fraction between the B(c)(+)→J/ψπ(+) and the B(+)→J/ψK(+) decays is measured to be (0.

Poly(amino acid) functionalized maghemite and gold nanoparticles.

Bimodal MRI/OI imaging probes are of great interest in nanomedicine. Although many organic polymers have been studied thoroughly for in vivo applications, reports on the use of poly(amino acid)s as coating polymers are scarce. In this paper, poly-(d-glutamic acid, d-lysine) (PGL) has been used for coating maghemite and gold nanoparticles.

Engineered fabrication of ordered arrays of Au-NiO-Au nanowires.

In the present paper, a novel method to fabricate ordered arrays of Au/NiO/Au nanowires is described, with the aim of filling the gap between the fundamental study of the electrical properties of scattered single nanowires and the engineered fabrication of nanowire arrays. This approach mainly consists of the following steps: (a) electrodeposition of Au/Ni/Au nanowires into an ordered porous anodic aluminum oxide template; (b) mechanical polishing of the sample to expose the gold tips of Au/Ni/Au nanowires to the template surface; (c) in situ annealing of the Au/Ni/Au nanowires without removing the template. The resulting structure consists in an ordered array of Au/NiO/Au nanowires slightly protruding out of a flat aluminum oxide template.

Measurements of the branching fractions of [Formula: see text] decays.

The branching fractions of the decay [Formula: see text] for different intermediate states are measured using data, corresponding to an integrated luminosity of 1.0 fb, collected by the LHCb experiment. The total branching fraction, its charmless component [Formula: see text] and the branching fractions via the resonant [Formula: see text] states (1) and (2) relative to the decay via a / intermediate state are [Formula: see text] Upper limits on the branching fractions into the (2) meson and into the charmonium-like states (3872) and (3915) are also obtained.

Performance of the LHCb RICH detector at the LHC.

The LHCb experiment has been taking data at the Large Hadron Collider (LHC) at CERN since the end of 2009. One of its key detector components is the Ring-Imaging Cherenkov (RICH) system. This provides charged particle identification over a wide momentum range, from 2-100 GeV/.

Measurement of the forward energy flow in collisions at [Formula: see text].

The energy flow created in collisions at [Formula: see text] is studied within the pseudorapidity range 1.9<<4.9 with data collected by the LHCb experiment.

Measurement of / polarization in collisions at [Formula: see text].

An angular analysis of the decay /→ is performed to measure the polarization of prompt / mesons produced in collisions at [Formula: see text]. The dataset corresponds to an integrated luminosity of 0.37 fb collected with the LHCb detector.

Observation of excited Λ(b)(0) baryons.

Using pp collision data corresponding to 1.0 fb(-1) integrated luminosity collected by the LHCb detector, two narrow states are observed in the Λ(b)(0)π(+)π(-) spectrum with masses 5911.97±0.

Measurement of the B¯(s)(0) effective lifetime in the J/ψf0(980) final state.

The effective lifetime of the B ¯(s)(0) meson in the decay mode B¯(s)(0)→J/ψf(0)(980) is measured using 1.0 fb(-1) of data collected in pp collisions at √s=7 TeV with the LHCb detector. The result is 1.

Observation of B0→D¯(0)K(+)K(-) and evidence for B(s)(0)→D¯(0)K(+)K(-).

The first observation of the decay B0→D¯(0)K(+)K(-) is reported from an analysis of 0.62 fb(-1) of pp collision data collected with the LHCb detector. Its branching fraction is measured relative to that of the topologically similar decay B(0)→D ¯(0)π(+)π(-) to be (B(B(0)→D¯(0)K(+)K(-))/B(B(0)→D¯(0)π(+)π(-))=0.

First observation of the decay B(c)+ → J/ψπ(+) π- π+.

The decay B(c)(+) → J/ψπ(+) π(-) π(+) is observed for the first time, using 0.8 fb(-1) of pp collisions at sqrt[s] = 7 TeV collected by the LHCb experiment. The ratio of branching fractions B(B(c)(+) → J/ψπ(+) π(-) π(+))/B(B(c)(+)→J/ψπ^{+}) is measured to be 2.

Determination of the sign of the decay width difference in the B(s)(0) system.

The interference between the K+ K- S-wave and P-wave amplitudes in B(s)(0) → J/ψK+ K- decays with the K+ K- pairs in the region around the ϕ(1020) resonance is used to determine the variation of the difference of the strong phase between these amplitudes as a function of K+ K- invariant mass. Combined with the results from our CP asymmetry measurement in B(s)(0) → J/ψϕ decays, we conclude that the B(s)(0) mass eigenstate that is almost CP = +1 is lighter and decays faster than the mass eigenstate that is almost CP = -1. This determines the sign of the decay width difference ΔΓ(s) ≡ Γ(L) - Γ(H) to be positive.

Strong constraints on the rare decays B(s)(0) → μ+ μ- and B0 → μ+ μ-.

A search for B(s)(0) → μ+ μ- and B0 → μ+ μ decays is performed using 1.0  fb(-1) of pp collision data collected at sqrt[s] = 7  TeV with the LHCb experiment at the Large Hadron Collider. For both decays, the number of observed events is consistent with expectation from background and standard model signal predictions.

Differential branching fraction and angular analysis of the decay B0 → K*0 μ+ μ-.

The angular distributions and the partial branching fraction of the decay B0 → K*0 μ+ μ- are studied by using an integrated luminosity of 0.37  fb(-1) of data collected with the LHCb detector. The forward-backward asymmetry of the muons, A(FB), the fraction of longitudinal polarization, F(L), and the partial branching fraction dB/dq2 are determined as a function of the dimuon invariant mass.