Damage Resistance of Kevlar Fabric, UHMWPE, PVB Multilayers Subjected to Concentrated Drop-Weight Impact.

The impact resistance of layered polymer structures using polyvinyl butyral (PVB) in combination with Kevlar fabric and ultra-high molecular weight polyethylene (UHMWPE) were fabricated and tested. Methods of wet impregnation and hot-press impregnation and consolidation of fabric with PVB and UHMWPE were used to manufacture multilayer constructs. All sandwich constructs were fixed to the surface of ballistic clay and subject to a free drop-weight test with a conical impactor having a small contact area.

Anti-Ballistic Performance of PPTA/UHMWPE Laminates.

Poly(-phenylene terephthalamide) (PPTA) and ultra-high-molecular-weight polyethylene (UHMWPE) are high-performance polymer materials largely used for body armor applications. Although composite structures from a combination of PPTA and UHMWPE have been created and described in the literature, the manufacture of layered composites from PPTA fabrics and UHMWPE films with UHMWPE film as an adhesive layer has not been reported. Such a new design can provide the obvious advantage of simple manufacturing technology.

Machine Learning at the Interface of Polymer Science and Biology: How Far Can We Go?

This Perspective outlines recent progress and future directions for using machine learning (ML), a data-driven method, to address critical questions in the design, synthesis, processing, and characterization of . The achievement of these tasks requires the navigation of vast and complex chemical and biological spaces, difficult to accomplish with reasonable speed. Using modern algorithms and supercomputers, quantum physics methods are able to examine systems containing a few hundred interacting species and determine the probability of finding them in a particular region of phase space, thereby anticipating their properties.

Improving Interlayer Adhesion of Poly(p-phenylene terephthalamide) (PPTA)/Ultra-high-molecular-weight Polyethylene (UHMWPE) Laminates Prepared by Plasma Treatment and Hot Pressing Technique.

Poly(p-phenylene terephthalamide) (PPTA) is a high-performance polymer that has been utilized in a range of applications. Although PPTA fibers are widely used in various composite materials, laminar structures consisting of PPTA and ultra-high-molecular-weight polyethylene (UHMWPE), are less reported. The difficulty in making such composite structures is in part due to the weakness of the interface formed between these two polymers.

Property Decoupling across the Embryonic Nucleus-Melt Interface during Polymer Crystal Nucleation.

Spatial distributions are presented that quantitatively capture how polymer properties (e.g., segment alignment, density, and potential energy) vary with distance from nascent polymer crystals (nuclei) in prototypical polyethylene melts.

Monodisperse Polymer Melts Crystallize via Structurally Polydisperse Nanoscale Clusters: Insights from Polyethylene.

This study demonstrates that monodisperse entangled polymer melts crystallize via the formation of nanoscale nascent polymer crystals (i.e., nuclei) that exhibit substantial variability in terms of their constituent crystalline polymer chain segments (stems).

Divining the shape of nascent polymer crystal nuclei.

We demonstrate that nascent polymer crystals (i.e., nuclei) are anisotropic entities with neither spherical nor cylindrical geometry, in contrast to previous assumptions.

Nanoparticle-Infused UHMWPE Layer as Multifunctional Coating for High-Performance PPTA Single Fibers.

High-performance fibers made of poly-(p-phenylene terephthalamide) (PPTA) with high stiffness and high strength are widely used in body armor for protection due to their high degree of molecular chain alignment along the fiber direction. However, their poor mechanical properties in the transverse direction and low surface friction are undesirable for applications requiring resistance to ballistic impact. Here we provide a simple yet effective surface engineering strategy to improve both the transverse mechanical properties and the tribological property by coating PPTA fibers with ultra-high molecular weight polyethylene (UHMWPE) embedded with silica nanoparticles.

Author Correction: Structure-Mechanical Property Relations of Skin-Core Regions of Poly(p-phenylene terephthalamide) Single Fiber.

A correction to this article has been published and is linked from the HTML and PDF versions of this paper. The error has been fixed in the paper.

Structure-Mechanical Property Relations of Skin-Core Regions of Poly(p-phenylene terephthalamide) Single Fiber.

This study aims to elucidate the relationship between the mechanical properties and microstructures of poly(p-phenylene terephthalamide) (PPTA) single fibers at the micro/nano scale. The skin-core structure of Kevlar® 29 fiber was revealed through a focused electron beam experiment inside a scanning electron microscope (SEM) chamber. Cross sectional SEM images of the broken fiber showed that the thickness of the skin ranged from 300 to 800 nm and that the core region consisted of highly packed layers of fibrils.

Mechanically Strong Polymer Sheets from Aligned Ultrahigh-Molecular-Weight Polyethylene Nanocomposites.

Ultrahigh-molecular-weight polyethylene (UHMWPE) is of great interest as a next-generation body armor material because of its superior mechanical properties. However, such unique properties depend critically on its microscopic structure characteristics, including the degree of crystallinity, chain alignment, and morphology. Here, we present a highly aligned UHMWPE and its composite sheets containing uniformly dispersed boron nitride (BN) nanosheets.