Here electrospinning and freeze-drying techniques are combined to fabricate an anisotropic SiC@SiO ceramic fiber aerogels (A-SiC@SiO-FAs). The anisotropic structure of the A-SiC@SiO-FAs features aligned layers stacking layer-by-layer with the same direction and highly oriented 1D fibers inside each layer. The A-SiC@SiO-FAs exhibit anisotropic thermal properties with an extremely low thermal conductivity of 0.
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