Manipulating Hydrogen-Bonding Donor/Acceptor in Ultra-Robust Isoreticular Zr(IV) Metal-Organic Frameworks for Efficient Regulation of Water Sorption Inflection Point and Steepness.

The development of porous materials exhibiting steep and stepwise adsorption of water vapor at desired humidity is crucial for implementing diverse applications such as humidity control, heat allocation, and atmospheric water harvesting. The precise molecular-level elucidation of structural characteristics and chemical components that dictate the water sorption behaviors in confined nanospaces, metal-organic frameworks (MOFs) in particular, is fundamentally important, but this has yet to be largely explored. In this work, by leveraging the isoreticular principle, we crafted two pairs of isostructural Zr-MOFs with linker backbones of benzene and pyrazine acting as hydrogen-bonding donor and acceptor, respectively.

Modulator-Directed Counterintuitive Catenation Control for Crafting Highly Porous and Robust Metal-Organic Frameworks with Record High SO Uptake Capacity.

Sulfur dioxide (SO) is an important industrial feedstock that can be directly utilized or catalytically transformed to value-added chemicals such as sulfuric acid. The development of regenerable porous sorbents for the highly efficient storage and energy-minimal release of toxic SO operating under ambient conditions has attracted growing interest. Herein, we report the topology-guided construction of highly porous -type metal-organic frameworks (MOFs) through a counterintuitive modulator-directed catenation control approach.

Leveraging Isoreticular Principle to Elucidate the Key Role of Inherent Hydrogen-Bonding Anchoring Sites in Enhancing Water Sorption Cyclability of Zr(IV) Metal-Organic Frameworks.

Water adsorption/desorption cyclability of porous materials is a prerequisite for diverse applications, including atmospheric water harvesting (AWH), humidity autocontrol (HAC), heat pumps and chillers, and hydrolytic catalysis. However, unambiguous molecular insights into the correlation between underlying building blocks and the cyclability are still highly elusive. In this work, by taking advantage of the well-established isoreticular synthetic principle in Zr(IV) metal-organic frameworks (Zr-MOFs), we show that the inherent density of hydrogen atoms in the organic skeleton can play a key role in regulating the water sorption cyclability of MOFs.

Water-Resistant, Scalable, and Inexpensive Chiral Metal-Organic Framework Featuring Global Negative Electrostatic Potentials for Efficient Acetylene Separation.

Physical separation of acetylene (CH) from carbon dioxide (CO) or ethylene (CH) on metal-organic frameworks (MOFs) is crucial for achieving high-purity feed gases with minimal energy penalty. However, such processes are exceptionally challenging due to their close physical properties and are also critically restricted by the high cost of large-scale MOF synthesis. Here, we demonstrate the readily scalable synthesis of a highly water-resistant chiral Cu-MOF () based on an inexpensive proteogenic amino acid derivative bearing rich N/O sites.

Multicolor-tunable room-temperature afterglow and circularly polarized luminescence in chirality-induced coordination assemblies.

Dynamic long-lived multicolor room temperature afterglow and circularly polarized luminescence (CPL) are promising for optoelectronic applications, but integration of these functions into a single-phase chiroptical material is still a difficult and meaningful challenge. Here, a nitrogen-doped benzimidazole molecule 1-1,2,3-triazolopyridine (Trzpy) showing pure organic room-temperature phosphorescence (RTP) acted as a linker, and then, we propose a chirality-induced coordination assembly strategy to prepare homochiral crystal materials. Two homochiral coordination polymers DCF-10 and LCF-10 not only exhibit multicolor-tunable RTP, the color changed from green to orange under various excitation wavelengths, but also show remarkable excitation-dependent circularly polarized luminescence (CPL), and the dissymmetry factors of CPL in DCF-10 and LCF-10 are 1.

Realization of Single-Phase White-Light-Emitting Materials with Time-Evolution Ultralong Room-Temperature Phosphorescence by Coordination Assemblies.

Two Cd-based supramolecular coordination polymers, [Cd(CzIP)(DMF)] () and [Cd(CzIP)(DMF)] (), were synthesized by using 5-(carbazol-9-yl) isophthalate (CzIP) as ligands. These two compounds exhibit multiple luminescence emissions; apart from fluorescence, time- and temperature-dependent ultralong phosphorescence (RTP) were also achieved under room conditions. Significantly, compound has a long-lived afterglow of 0.