Publications by authors named "Pelin Karakilic"

We demonstrate that b-oriented MFI (Mobil Five) zeolite membranes can be manufactured by in situ crystallization using an intermediate amorphous SiO layer. The improved in-plane growth by using a zeolite growth modifier leads to fusion of independent crystals and eliminates boundary gaps, giving good selectivity in the separation of CO/Xe mixtures. The fast diffusion of CO dominates the overall membrane selectivity toward the CO/Xe mixture.

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Article Synopsis
  • The study focuses on creating high-quality zeolite membranes with customizable chemical properties, which are necessary for improving their use in separation and catalysis.
  • It details a method for directly attaching a b-oriented silicalite-1 layer to a commercial porous substrate, followed by a secondary growth process to produce ZSM-5 membranes with variable Si/Al compositions.
  • The research also highlights the use of sodium to enhance crystal growth and reduce defects, leading to membranes that can switch between hydrophobic and hydrophilic characteristics, broadening their potential applications.
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