Nanomaterials (Basel)
April 2020
Current collectors are an important component of electrodes, functioning as conductive media by collecting currents from active materials and then exporting them to the external circuit. Common current collectors for graphene hydrogel (GH)-based supercapacitors are nickel foams or metal foils (platinum, gold, and aluminium, etc.).
View Article and Find Full Text PDFThe development of high-performance acetone gas sensor is of great significance for environmental protection and personal safety. SnO₂ has been intensively applied in chemical sensing areas, because of its low cost, high mobility of electrons, and good chemical stability. Herein, we incorporated nitrogen atoms into the SnO₂ nanostructure by simple solvothermal and subsequent calcination to improve gas sensing property for acetone.
View Article and Find Full Text PDFIncorporation of new functional components into a three-dimensional graphene (3DG) framework improves the performance of supercapacitors based on 3DG as electrodes by tailoring the framework's structure and properties. In this work, graphene quantum dots (GQDs) were incorporated into 3DG via one-step hydrothermal treatment of GQDs and graphene oxide (GO). By simply adjusting the GQDs/GO feeding ratio by weight, various GQDs/3DG composites were formed.
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2014
Graphene quantum dots (GQDs) have fascinating photoluminescence (PL) properties with promising applications in bioimaging, fluorescent sensing and the photoelectrics field. In this work, PL properties of GQDs obtained from different carbonaceous precursors including carbon fibers, graphite powder, graphene oxide (GO) and reduced graphene oxide (RGO) were regulated via a simple hydrothermal reduction. Upon hydrothermal treatment, the fluorescent peaks of the original GQDs were blue-shifted to 440 nm and their PL intensities were enhanced by about 2 times.
View Article and Find Full Text PDFChemical modification is an important technique to modulate the chemical and optical properties of graphene quantum dots (GQDs). In this paper, we report a versatile diazonium chemistry method to graft aryl groups including phenyl, 4-carboxyphenyl, 4-sulfophenyl and 5-sulfonaphthyl to GQDs via Gomberg-Bachmann reaction. The aryl-modified GQDs are nanocrystals with lateral dimensions in the range of 2-4 nm and an average thickness lower than 1 nm.
View Article and Find Full Text PDFWe report an improved Hummers method for synthesizing graphene quantum dots (GQDs) by directly oxidizing and etching graphite powders. The yield of GQDs is as high as 63 ± 7% (by weight, wt%), suggesting this technique is suitable for producing GQDs on a large scale. The GQDs are nanocrystals with lateral dimensions in the range of 2-4 nm and an average thickness of around 1.
View Article and Find Full Text PDFGraphene hydrogel/nickel foam composite electrodes for high-rate electrochemical capacitors are produced by reduction of an aqueous dispersion of graphene oxide in a nickel foam (upper half of figure). The micropores of the hydrogel are exposed to the electrolyte so that ions can enter and form electrochemical double-layers. The nickel framework shortens the distances of charge transfer.
View Article and Find Full Text PDFPhys Chem Chem Phys
May 2012
Gold@carbon dots composite nanoparticles (Au@CDs) with ultrathin carbon dot (CD) shells of ca. 2 nm were prepared by reducing HAuCl(4) with CDs at 100 °C. By adjusting the feeding mass ratio of HAuCl(4) to CDs, the average diameters of Au@CDs can be modulated from 8 to 44 nm.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
November 2009
Study on dye-sensitized solar cells (DSSCs) with extracts of Canna indica L., Salvia splendens, Solanum nigrum L. as sensitizers is firstly reported in this paper.
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