Metal Complex/ZnS-Modified Ni Foam as Magnetically Stirrable Photocatalysts: Roles of Redox Mediators and Carrier Dynamics Monitored by Operando Synchrotron X-ray Spectroscopy.

Magnetically stirrable photocatalysts binding the ZnS-decorated Ni foam with the metal complex cocatalyst as a redox mediator and light-absorbing composition were investigated. Loading metal complex can improve light absorption, surface hydrophilicity, interfacial charge migration, and H production activity. The variation of the metal valences of the composite photocatalysts in an operando environment (with sacrificial agent solution) with and without light irradiation was investigated by X-ray absorption near-edge structure (XANES) spectra and Fourier-transformed extended X-ray absorption fine structure (EXAFS) spectra to monitor the charge carrier dynamics of photocatalysis and explain how the macrocyclic Cu complex (CuC) acted as a redox mediator better than the Ni complex.

Polymer/BiOBr-Modified Gauze as a Dual-Functional Membrane for Heavy Metal Removal and Photocatalytic Dye Decolorization.

It is crucial to remove heavy metals and dyes before discharging industrial effluents. Gauze substrate was surface-modified by coating with a polymeric adsorbent and a spray coating of BiOBr photocatalyst to develop a novel dual-functional membrane, polymer/BiOBr-modified gauze, for water remediation. The polymeric adsorbent was crosslinked to prevent the dissolving of the adsorbent during operation in contaminated water.