This study explores advancements in concurrent biorefinery and hydrogen production using Ni-decorated CNTs derived from bioethanol as electrocatalysts, showing the complete conversion of furan derivatives to the desired products with 95-97% selectivity and a hydrogen production rate of 75 μmol h. These findings highlight the simultaneous upgrading of biomass-derived compounds and hydrogen production.
View Article and Find Full Text PDFMetal single-site catalysts have recently played an essential role in catalysis due to their enhanced activity, selectivity, and precise reaction control compared to those of conventional metal cluster catalysts. However, the rational design and catalytic application of metal single-site catalysts are still in the early stages of development. In this contribution, we report the rational design of Fe single sites incorporated in a hierarchical ZSM-5 atomic layer deposition (ALD).
View Article and Find Full Text PDFThe development of industrial catalysts is of crucial importance for practical uses. However, the use of extruded catalysts in industry is still limited because of a remarkably decreased catalytic activity when combining them with binders. This contribution illustrates the rational design of binder-free hierarchical ZSM-5 pellets and monoliths derived from zeolite@LDHs composites extrusion and 3D printing technologies, respectively.
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