In Situ Electric-Field Control of THz Nonreciprocal Directional Dichroism in the Multiferroic Ba_{2}CoGe_{2}O_{7}.

Nonreciprocal directional dichroism, also called the optical-diode effect, is an appealing functional property inherent to the large class of noncentrosymmetric magnets. However, the in situ electric control of this phenomenon is challenging as it requires a set of conditions to be fulfilled: Special symmetries of the magnetic ground state, spin excitations with comparable magnetic- and electric-dipole activity, and switchable electric polarization. We demonstrate the isothermal electric switch between domains of Ba_{2}CoGe_{2}O_{7} possessing opposite magnetoelectric susceptibilities.

Infrared spectroscopy of small-molecule endofullerenes.

Hydrogen is one of the few molecules that has been incarcerated in the molecular cage of C₆₀ to form the endohedral supramolecular complex H₂@C₆₀. In this confinement, hydrogen acquires new properties. Its translation motion, within the C₆₀ cavity, becomes quantized, is correlated with its rotation and breaks inversion symmetry that induces infrared (IR) activity of H₂.