Low-cost zeolite-based sorbents prepared from industrial perlite by-product material for Zn and Ni removal from aqueous solutions: synthesis, properties and sorption efficiency.

The conversion of waste/by-product materials into efficient sorbents is at the forefront of innovative remediation techniques. In the present study, the relationships among the synthesis conditions, physicochemical properties of synthesized sorbents and Zn and Ni removal efficiencies were studied in detail. Zeolite X, zeolite P, phillipsite, analcime, sodalite and cancrinite were synthesized from industrial perlite by-product material.

Transesterification of Oil Catalyzed by Mg/Al Mixed Oxides with Added Divalent Metals.

This paper is focused on the heterogeneously catalyzed transesterification (in a batch reactor) of vegetable oil, including the determination of leached metals. The oil was obtained from the short-season crop . The reaction was catalyzed by mixed oxides, which were synthesized from Mg/Al hydrotalcites with built-in different types of divalent cations such as Mn, Ca, Co, Ni, and Fe.

Application of quasi-equilibrated thermodesorption of linear and di-branched paraffin molecules for detailed porosity characterization of the mono-layered zeolite MCM-56, in comparison with MCM-22 and ZSM-5.

The pore characteristics of zeolite samples including two kinds of ZSM-5 crystals as a base case and the unique mono-layered MCM-56 in different structural forms have been studied by the new method QE-TPDA (quasi-equilibrated temperature-programmed desorption and adsorption) in comparison with the standard nitrogen adsorption. Both approaches produce consistent results in terms of micro- and meso-porous features as well as quantitative pore volume values. The benefits of QE-TPDA include fast data acquisition (hours) and small sample size (milligrams).