Influence of delignification and reaction conditions in the aqueous phase transformation of lignocellulosic biomass to platform molecules.

The effect of oxidative and reductive delignification processes on the hydrolysis of pine sawdust at mild conditions (200-1000 ppm of HCl and 140-220 °C) is studied in this work. Dimers and reduced sugars are the main products obtained with the fresh sawdust (>82%), reaching a maximum liquid phase yield of 17% after 8 h, at the strongest conditions. This conversion increases up to almost 40% with the pretreated sawdust, obtaining selectivities higher than 87% of levulinic acid and a well-defined distribution of the relevant platform molecules (sugars, HMF, furfural, levulinic acid) as function of the severity of the reaction, decreasing the humins formation and being possible to define different conditions to maximize each yield.