Iron functionalized silica particles as an ingenious sorbent for removal of fluoride from water.

The paucity of safe drinking water remains a global concern. Fluoride is a pollutant prevalent in groundwater that has adverse health effects. To resolve this concern, we devised a silica-based defluoridation sorbent from pumice rock obtained from the Paka volcano in Baringo County, Kenya.

Antimalarial Activity of Stem Bark Extracts against .

There is an increasing need for innovative drug and prophylaxis discovery against malaria. The aim of the present study was to test antiplasmodial activity of H. (Euphorbiaceae) stem bark extracts from Kenyan folkloric medicine.

Antimicrobial activity of 2,5-dihydroxy-3-methyl-1,4-benzoquinone from Embelia schimperi.

Chromatographic separation of an ethyl acetate extract from Embelia schimperi led to the isolation of a new compound identified as 2,5-dihydroxy-3-methyl-1,4-benzoquinone (1) on the basis of spectroscopic and physical data. The plant's crude extract and pure compound 1 were assayed for in vitro antimicrobial activity against clinical strains of Salmonella spp., Proteus spp.

Limonoids as larvicidal components against mosquito larvae (Aedes aegypti Linn.).

The study focussed on four limonoids (calodendrolide, harrisonin, pedonin and pyroangolensolide) as larvicidal components against mosquito 2nd instar larvae of the species Aedes aegypti Linn. senso stricto. Since pyroangolensolide is close to calodendrolide in structure, it was synthesized through reduction of calodendrolide with chromium(II) chloride in acetone.

Pentacyclic triterpenoids from Embelia schimperi.

Five oleanane-type pentacyclic triterpenoids were isolated by chromatographic separation of a chloroform extract of the stem bark of Embelia schimperi. Three of these compounds have a methyleneoxy bridge. Two compounds, embelinone and schimperinone, are reported here for the first time from a natural source (they have been synthesized previously during chemical transformations).