Publications by authors named "Paul E Sokol"

As the spatial dimension is lowered, locally stabilizing interactions are reduced, leading to the emergence of strongly fluctuating phases of matter without classical analogues. Here we report on the experimental observation of a one dimensional quantum liquid of He using nanoengineering by confining it within a porous material preplated with a noble gas to enhance dimensional reduction. The resulting excitations of the confined He are qualitatively different than bulk superfluid helium, and can be analyzed in terms of a mobile impurity allowing for the characterization of the emergent quantum liquid beyond the Luttinger liquid paradigm.

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Highly concentrated micelles in CTAB/NaSal solutions with a fixed salt/surfactant ratio of 0.6 have been studied using Small Angle Neutron Scattering (SANS) as a function of temperature and concentration. A worm-like chain model analysis of the SANS data using a combination of a cylindrical form factors for the polydisperse micellar length, circular cross-sectional radius with Gaussian polydispersity, and the structure factor based on a random phase approximation (RPA) suggests that these micelle solutions have a worm-like micellar structure that is independent of the concentration and temperature.

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Article Synopsis
  • The study utilizes small angle X-ray scattering (SAXS) to analyze the structure of vertically aligned multiwall carbon nanotube (MWCNT) arrays.
  • By examining SAXS intensity at different angles, researchers assess the degree of alignment and identify two distinct morphologies across different heights of the CNT arrays.
  • Findings indicate that the average diameter of the MWCNTs increases as one moves further away from the substrate, highlighting real variations in CNT sizes through model fitting.
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Article Synopsis
  • - The study utilized Deep Inelastic Neutron Scattering (DINS) to analyze water confined in mesoporous silica at room temperature, focusing on the interactions between water protons and silanol groups on the surface.
  • - Researchers controlled water adsorption to achieve a 1:1 ratio of water molecules to silanol groups, allowing for a precise measurement of the system's proton dynamics and organization.
  • - The findings indicate that the hydrogen bonds formed between water protons and the silanol oxygen are significantly stronger than those found in bulk water, suggesting unique structural properties in confined water environments.
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Wide-angle X-ray scattering measurements were performed to record structural changes during the transition from trehalose dihydrate to crystalline anhydrous alpha-trehalose. The results show that large dihydrate crystals rearrange into smaller sized alpha crystals; from the peak widths we calculate a crystallite size of typically approximately 40 trehalose molecules. We find that the dehydration probably takes place in a two-step process with different time scales for both the water removal step and the molecule rearrangement step.

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We report measurements of the x-ray scattering intensity as mesoporous silica glasses are filled with neon. The intensity of the first peak in the liquidlike diffraction pattern increases nonlinearly with mass adsorbed. We outline a simple model assuming that the major coherent contribution to the first peak in the scattering function S(Q) is due to interference from nearest-neighbor scatterers.

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