MIL-101(Cr)@QCM and MIL-101(Cr)@IDE as Sorbent-Based Humidity Sensors for Indoor Air Monitoring.

MIL-101(Cr) films were deposited on the quartz crystal microbalance and interdigitated electrode transductors as humidity sensors. Both devices combine high sensitivity with fast response/recovery times, good repeatability, long-term stability, favorable selectivity versus toluene alongside a dual mode behavior in the optimal domain of humidity for indoor air.

MIL-101(Cr) MOF as an Effective Siloxane Sensor.

Volatile methylsiloxanes (VMSs) are common silicone degradation byproducts that cause serious concern for the contamination of sensitive electronics and optics, among others. With the goal of fast, online detection of VMS, we herein highlight the mesoporous MIL-101(Cr) MOF as a promising mass sensing layer for integration with a quartz crystal microbalance (QCM), using an in-house modified gravimetric adsorption system capable of achieving extremely low concentrations of siloxane D4 (down to 0.04 ppm), targeting applications for monitoring in indoor spaces and spacecraft.