In engineering applications, natural fiber composites must comply with fire requirements including the use of flame retardant. Furthermore, biocomposites are known to be water sensitive. Whether flame retardants affect the water sensitivity and whether water absorption affects the fire behavior and the mechanical performance of biocomposites are the two main topics addressed in this work.
View Article and Find Full Text PDFRecycling of plastics is hindered by their important variety and strong incompatibility. However, sorting technologies bear costs and meet limits. Very high purities (<2 wt%) are difficult to reach.
View Article and Find Full Text PDFWith the development of dark polymers for industrial sorting technologies, economically profitable recycling of plastics from Waste Electrical and Electronical Equipment (WEEE) can be envisaged even in the presence of residual impurities. In ABS extracted from WEEE, PP is expected to be the more detrimental because of its important lack of compatibility. Hence, PP was incorporated to ABS at different rates (2 to 8 wt%) with a twin-screw extruder.
View Article and Find Full Text PDFThe molecular architecture and rheological behavior of linear and branched polybutylene succinate blends have been investigated using size-exclusion chromatography, small-amplitude oscillatory shear and extensional rheometry, in view of their processing using cast and blown extrusion. Dynamic viscoelastic properties indicate that a higher branched polybutylene succinate amount in the blend increases the relaxation time due to an increased long-chain branching degree. Branched polybutylene succinate exhibits pronounced strain hardening under uniaxial elongation, which is known to improve processability.
View Article and Find Full Text PDFAgeing of polymers entails important structural changes and degrades their functional properties, particularly their aspect. Since sorting is a primordial step in recycling to achieve acceptable mechanical properties, the use of promising technologies such as MIR-HSI (Mid-Infrared Hyperspectral Imagery), which could overcome black plastics sorting issue, has to take into account the influence of ageing on identification. As ageing strongly impacts spectra, it can create confusion between materials, especially in an automatized scheme.
View Article and Find Full Text PDFSorting at industrial scale is required to perform mechanical recycling of plastics in order to obtain properties that could be competitive with virgin polymers. As a matter of fact, the most part of the various types of plastic waste are not miscible and even compatible. Mid-Infrared (MIR) HyperSpectral Imagery (HSI) is viewed as one of the solutions to the problem of black plastic sorting.
View Article and Find Full Text PDFOne of the major limitations in polymer recycling is their sorting as they are collected in mixes. The majority of polymers are highly incompatible without compatibilizers. For sorting of polymers, high-speed online Near-Infrared (NIR) spectroscopy is nowadays relatively widespread.
View Article and Find Full Text PDFFor many practitioners, longevity of full glass ceramic crowns in the posterior area, molars and premolars, remains a real challenge. The purpose of this article is to identify and evaluate the parameters that can significantly influence their resistance when preparing a tooth. The analysis proposed in this article relies on interrelated studies conducted at three levels: in vitro (mechanical tests), in silico (finite elements simulations) and in vivo (clinical survival rates).
View Article and Find Full Text PDFIn order to produce a high quality recycled material from real deposits of electric and electronic equipment, the rate of impurities in different blended grades of reclaimed materials has to be reduced. Setting up industrial recycling procedures requires to deal with the main types of polymers presents in WEEE (Waste Electric and Electronic Equipment), particularly High Impact Polystyrene (HIPS) as well as other styrenic polymers such as Acrylonitrile-Butadiene-Styrene (ABS), Polystyrene (PS) but also polyolefin which are present into WEEE deposit as Polypropylene (PP). The production of a substantial quantity of recycled materials implies to improve and master the compatibility of different HIPS grades.
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