Venus Flagship Mission Concept: A Decadal Survey Study.

More than any other known planet, Venus is essential to our understanding of the evolution and habitability of Earth-size planets throughout the galaxy. We address two critical questions for planetary science: 1) How, if at all, did Venus evolve through a habitable phase? 2) What circumstances affect how volatiles shape habitable worlds? Volatile elements have a strong influence on the evolutionary paths of rocky bodies and are critical to understanding solar system evolution. It is clear that Venus experienced a different volatile element history from the Earth and provides the only accessible example of one end-state of habitable Earth-size planets.

Titan Lakes Simulation System (TiLSS): A cryogenic experimental setup to simulate Titan's liquid hydrocarbon surfaces.

Titan's hydrocarbon lakes play an important role in the chemistry, geomorphology, and climate of the satellite. Our knowledge of their composition relies mainly on thermodynamic modeling and assumptions based on Radar and VIMS (Visible and Infrared Mapping Spectrometer) data. Several thermodynamic models have been used to calculate the composition of these lakes, and their results on even the major lake components (methane, ethane, propane, and nitrogen) exhibit large discrepancies.

Formation of a new benzene-ethane co-crystalline structure under cryogenic conditions.

We report the first experimental finding of a solid molecular complex between benzene and ethane, two small apolar hydrocarbons, at atmospheric pressure and cryogenic temperatures. Considerable amounts of ethane are found to be incorporated inside the benzene lattice upon the addition of liquid ethane onto solid benzene at 90-150 K, resulting in formation of a distinctive co-crystalline structure that can be detected via micro-Raman spectroscopy. Two new features characteristic of these co-crystals are observed in the Raman spectra at 2873 and 1455 cm(-1), which are red-shifted by 12 cm(-1) from the υ1 (a1g) and υ11 (eg) stretching modes of liquid ethane, respectively.