Laboratory growth capacity of an invasive cyanobacterium () on organic substrates from surface waters of permafrost peatlands.

Within a global warming trend, invasive cyanobacteria, abundant in tropical and temperate regions, can migrate northward and colonize thermokarst lakes in permafrost-affected territories. For a better understanding of the cyanobacterial proliferation mechanism in those lakes, we performed laboratory growth of typical invasive cyanobacteria, , onto various organic-rich solutions representative of permafrost peatlands. Aqueous leachates of lichen, moss and peat were the most favorable substrates for massive growth.

Kinetics and mechanisms of cyanobacterially induced precipitation of magnesium silicate.

The biomineralization of CO , in the form of carbonate minerals, is considered as one of the efficient solutions of atmospheric CO removal, allowing stable and sustainable storage of this greenhouse gas. Cyanobacteria are among the most powerful microorganisms capable of precipitating carbonate minerals, both in the present and in the past. In the modern environments, high Si concentration during geoengineering biomineralization could occur due to dissolution of Mg-bearing primary silicates such as olivine.

Impact of freeze-thaw cycles on organic carbon and metals in waters of permafrost peatlands.

Despite the importance of soil and surface waters freezing in permafrost landscapes, the behaviour of dissolved organic carbon (DOC), nutrients and metals during periodic freeze-thaw cycles (FTC) remains poorly known. The on-going climate warming is likely to increase the frequency of FTC in continental aquatic settings, which could modify the chemical composition of waters. In this study, we conducted 9 repetitive cycles of overnight freezing (-20 °C) and 5 h thawing (4 °C) in the laboratory using representative 0.

Complexation of Nickel Ions by Boric Acid or (Poly)borates.

An experiment based on electrochemical reactions and pH monitoring was performed in which nickel ions were gradually formed by oxidation of a nickel metal electrode in a solution of boric acid. Based on the experimental results and aqueous speciation modeling, the evolution of pH showed the existence of significant nickel-boron complexation. A triborate nickel complex was postulated at high boric acid concentrations when polyborates are present, and the equilibrium constants were determined at 25, 50 and 70 °C.

Evidence for Carbonate Surface Complexation during Forsterite Carbonation in Wet Supercritical Carbon Dioxide.

Continental flood basalts are attractive formations for geologic sequestration of carbon dioxide because of their reactive divalent-cation containing silicates, such as forsterite (Mg2SiO4), suitable for long-term trapping of CO2 mineralized as metal carbonates. The goal of this study was to investigate at a molecular level the carbonation products formed during the reaction of forsterite with supercritical CO2 (scCO2) as a function of the concentration of H2O adsorbed to the forsterite surface. Experiments were performed at 50 °C and 90 bar using an in situ IR titration capability, and postreaction samples were examined by ex situ techniques, including scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), focused ion beam transmission electron microscopy (FIB-TEM), thermal gravimetric analysis mass spectrometry (TGA-MS), and magic angle spinning nuclear magnetic resonance (MAS NMR).

In situ study of CO₂ and H₂O partitioning between Na-montmorillonite and variably wet supercritical carbon dioxide.

Shale formations play fundamental roles in large-scale geologic carbon sequestration (GCS) aimed primarily to mitigate climate change and in smaller-scale GCS targeted mainly for CO2-enhanced gas recovery operations. Reactive components of shales include expandable clays, such as montmorillonites and mixed-layer illite/smectite clays. In this study, in situ X-ray diffraction (XRD) and in situ infrared (IR) spectroscopy were used to investigate the swelling/shrinkage and H2O/CO2 sorption of Na(+)-exchanged montmorillonite, Na-SWy-2, as the clay is exposed to variably hydrated supercritical CO2 (scCO2) at 50 °C and 90 bar.

Automated high-pressure titration system with in situ infrared spectroscopic detection.

A fully automated titration system with infrared detection was developed for investigating interfacial chemistry at high pressures. The apparatus consists of a high-pressure fluid generation and delivery system coupled to a high-pressure cell with infrared optics. A manifold of electronically actuated valves is used to direct pressurized fluids into the cell.

Zeta potential of anoxygenic phototrophic bacteria and Ca adsorption at the cell surface: possible implications for cell protection from CaCO3 precipitation in alkaline solutions.

Electrophoretic mobility measurements and surface adsorption of Ca on living, inactivated, and heat-killed haloalkaliphilic Rhodovulum steppense, A-20s, and halophilic Rhodovulum sp., S-17-65 anoxygenic phototrophic bacteria (APB) cell surfaces were performed to determine the degree to which these bacteria metabolically control their surface potential equilibria. Zeta potential of both species was measured as a function of pH and ionic strength, calcium and bicarbonate concentrations.