Using X-ray emission spectroscopy, we find appreciable local magnetic moments until 30 GPa to 40 GPa in the high-pressure phase of iron; however, no magnetic order is detected with neutron powder diffraction down to 1.8 K, contrary to previous predictions. Our first-principles calculations reveal a "spin-smectic" state lower in energy than previous results.
View Article and Find Full Text PDFThe existence of "intermediate bonding states" in solid CO2, separating the low-pressure molecular phases from the high-pressure polymeric forms, has been the matter of a long-standing debate. Here we determine the structure of CO2-IV using x-ray diffraction of single crystals grown inside a diamond anvil cell at 11.7 GPa and 830 K.
View Article and Find Full Text PDFA pressure transmitting medium named Daphne 7474, which solidifies at P(s)=3.7 GPa at room temperature, is presented. The value of P(s) increases almost linearly with temperature up to 6.
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