Applications of H-Enriched syngas and slag products from plastic wastes via novel plasma dual-stage-arc pyrolysis.

Sustainable plastic waste management in the prevailing 'new-normal' post-pandemic scenario calls for calorific waste plastic up-cycling into high-end product recovery pathways. The present work employed a novel dual-stage arc plasma pyrolysis reactor to recover syngas and slag products from mixed plastics and Low-Density Polyethylene and Polyethylene Terephthalate (LDPE-PET) plastic waste feeds. Syngas product yield decreased while the solid slag yield increased with rising arc current, attaining 75% and 25% for mixed plastic waste feed and 59% and 41% for LDPE-PET wastes, respectively, at 200A arc current.

Investigations on the effect of kaolin catalyst on the yield of various products obtained from pyrolysis of low-density polyethylene (LDPE) wastes and reaction kinetics.

The pyrolysis characteristics of low-density polyethylene (LDPE) wastes were investigated in a batch pyrolyzer in the temperature range of 550-650 °C for a varying heating rate (5, 10, 15, 20, and 25 °C/min) alone and using kaolin catalyst (10, 15, and 20% w/w). The yield distribution of various products under varying operating conditions was investigated, and the corresponding favourable conditions for maximum yield of pyrolytic oil (PO) were identified. The possible effect of the catalyst on pyrolysis kinetics was explored by extracting activation energies from the TGA experiments.

Production of Blending Quality Bioethanol from Broken Rice: Optimization of Process Parameters and Kinetic Modeling.

The enzymatic and bio-enzymatic saccharification of waste broken rice (79.8% of starch) was successfully carried out to produce a reducible sugar solution (160 g/L). Bioethanol of concentration 71.

Optimization of process parameters for bio-enzymatic and enzymatic saccharification of waste broken rice for ethanol production using response surface methodology and artificial neural network-genetic algorithm.

Reducible sugar solution has been produced from waste broken rice by a novel saccharification process using a combination of bio-enzyme (bakhar) and commercial enzyme (α-amylase). The reducible sugar solution thus produced is a promising raw material for the production of bioethanol using the fermentation process. Response surface methodology (RSM) and Artificial neural network-genetic algorithm (ANN-GA) have been used separately to optimize the multivariable process parameters for maximum yield of the total reducing sugar (TRS) in saccharification process.

Conventional pyrolysis of Plastic waste for Product recovery and utilization of pyrolytic gases for carbon nanotubes production.

Inevitably increase in plastic demand has resulted in an overgrowing production on a global scale. The utilization of plastics has been applied to a number of industries as it is a durable, moldable, and inexpensive material. High exploitation of plastic had resulted in a hefty amount of waste production, which is not easy to recycle due to its non-degradable nature and results in landfills.

Thermal degradation of waste plastics under non-sweeping atmosphere: Part 2: Effect of process temperature on product characteristics and their future applications.

The current energy demand and diminishing conventional fuels have forced researchers to find an alternative source of energy. Waste to energy is the current trend for converting waste materials (plastic waste) into valuable fuels. This article mainly discussed the detailed characterization of the pyrolytic products, their comparative analysis and the reaction mechanism at varying operating temperature.

An experimental and theoretical investigation on torrefaction of a large wet wood particle.

A competitive kinetic scheme representing primary and secondary reactions is proposed for torrefaction of large wet wood particles. Drying and diffusive, convective and radiative mode of heat transfer is considered including particle shrinking during torrefaction. The model prediction compares well with the experimental results of both mass fraction residue and temperature profiles for biomass particles.

Modelling of pyrolysis of large wood particles.

A fully transient mathematical model has been developed to describe the pyrolysis of large biomass particles. The kinetic model consists of both primary and secondary reactions. The heat transfer model includes conductive and internal convection within the particle and convective and radiative heat transfer between the external surface and the bulk.

Modelling of pyrolysis of coal-biomass blends using thermogravimetric analysis.

The primary objective of this work was to develop an appropriate model to explain the co-pyrolysis behaviour of lignite coal-biomass blends with different proportions using a thermogravimetric analyzer. A new parallel-series kinetic model was proposed to predict the pyrolysis behaviour of biomass over the entire pyrolysis regime, while a kinetic model similar to that of Anthony and Howard [Anthony, D.B.

Innovative and cost-effective management of large omphalocele.

Background/purpose: The aim of this study was to develop a method of management of large omphalocele, with easily available inexpensive materials. The efficacy of using the plastic of urine collection bag and paper stapler, in creating the "silo" for the management of 3 newborns with such defects, were assessed.

Methods: All operations were done within 36 hours of birth.