Biopolymers offer significant advantages in water treatment applications. This study investigates polyethersulfone (PES) membranes enhanced with TiO₂ and Fe₃O₄ nanoparticles modified by sodium alginate (NaAlg), abbreviated as NaAlg@TiO₂ and NaAlg@Fe₃O₄, for the removal of diclofenac sodium salt (DCF) from water. The NaAlg biopolymer modification was achieved by wrapping the metal oxide nanoparticles.
View Article and Find Full Text PDFA pH-sensitive polyethersulfone (PES) membrane was prepared with the aid of newly synthesized Ag(I) coordination polymer (Ag(I)-CP) particles. Indicating obvious adsorptive property toward dyes, the Ag(I)-based metalorganic framework (MOF) was selected to be used as an additive to improve the dye selectivity of PES membranes for both cationic and anionic dyes. The performance examination and characterization of prepared membranes indicated the influence of Ag(I)-CP in PES membrane improvement.
View Article and Find Full Text PDFUsing an emulsion liquid membrane based on edible oils is investigated for removing cationic dyes from aqueous solutions. There is a great potential for using edible oils in food industry extraction processes. The parameters affecting the stability of the emulsion and the extraction rate were studied.
View Article and Find Full Text PDFIn this research, chitosan nanobiopolymers (CS-NPs) were synthesized using tripoly phosphate and transferred into the organic solvent via solvent exchange method. Different amounts of chitosan nanopolymers were embedded into the polyethersulfone (PES) membrane prepared by phase inversion precipitation method. The membranes were employed for nitrate removal from water under various solution pHs (4.
View Article and Find Full Text PDFMembrane adsorbents have emerged as powerful and attractive tools for the removal of hazardous materials such as dyes and heavy metal ions, mainly in trace amounts, from water resources. Among membrane adsorbents, those prepared from or modified with chitosan biopolymer and its derivatives are cases of interest because of chitosan advantages including biocompatibility, biodegradability, nontoxicity, reactivity, film and fiber forming capacity and favorable hydrophilicity. This review is oriented to provide a framework for better insight into fabrication methods and applications of chitosan-based adsorptive membranes.
View Article and Find Full Text PDFMWCNTs were wrapped by poly(sodium 4-styrenesulfonate) (PSS), and different amounts of raw and polymer wrapped MWCNTs were implemented to fabricate PES mixed matrix membranes by phase inversion method. Success of wrapping was probed by FTIR spectroscopy, and prepared membranes were characterized by SEM, AFM, porosity, and water contact angle measurements. Response surface methodology (RSM) was employed to optimize the permeate flux and dye removal efficiency of membranes with three variables of concentration, pH of dye solution, and membrane composition.
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