Rice powder template for hausmannite Mn3O4 nanoparticles and its application to aqueous zinc ion battery.

In this study, a simple calcination route was adopted to prepare hausmannite Mn3O4 nanoparticles using rice powder as soft bio-template. Prepared Mn3O4 was characterized by Fourier Transform Infra-Red Spectroscopy (FTIR), Field Emission Scanning Electron Microscopy (FESEM), Energy Dispersive X-ray microanalysis (EDX), Powder X-Ray Diffraction (XRD), Transmission Electron Microscopy (TEM), Brunauer-Emmett-Teller (BET) and Solid state UV-Vis spectroscopic techniques. Mn-O stretching in tetrahedral site was confirmed by FTIR and Raman spectra.

Electrochemical Detection of Dihydroxybenzene Isomers at a Pencil Graphite Based Electrode.

In this work, an HB pencil electrode (HBPE) was electrochemically modified by amino acids (AAs) glycine (GLY) and aspartic acid (ASA) and designated as GLY-HB and ASA-HB electrodes. They were used in the detection of dihydroxybenzene isomers (DHBIs) such as hydroquinone (HQ), catechol (CC), and resorcinol (RS), by cyclic voltammetry (CV), and by differential pulse voltammetry. HBPE was characterized by scanning electron microscopy and energy-dispersive X-ray spectroscopy.

Synthesis of main-chain chiral quaternary ammonium polymers for asymmetric catalysis using quaternization polymerization.

Main-chain chiral quaternary ammonium polymers were successfully synthesized by the quaternization polymerization of cinchonidine dimer with dihalides. The polymerization occurred smoothly under optimized conditions to give novel type of main-chain chiral quaternary ammonium polymers. The catalytic activity of the polymeric chiral organocatalysts was investigated on the asymmetric benzylation of N-(diphenylmethylidene)glycine tert-butyl ester.