Hydrogen production via aqueous-phase reforming for high-temperature proton exchange membrane fuel cells - a review.

Aqueous-phase reforming (APR) can convert methanol and other oxygenated hydrocarbons to hydrogen and carbon dioxide at lower temperatures when compared with the corresponding gas phase process. APR favours the water-gas shift (WGS) reaction and inhibits alkane formation; moreover, it is a simpler and more energy efficient process compared to gas-phase steam reforming. For example, Pt-based catalysts supported on alumina are typically selected for methanol APR, due to their high activity at temperatures of circa 200°C.