Generation of ultra-stable Pickering microbubbles via poly alkylcyanoacrylates.

A range of solution conditions (pH, surfactant concentration and type) have been tested for the polymerization of alkyl cyanoacrylates (ethyl (ECA), butyl (BCA) and octyl (OCA)) into nanoparticles (NPs) potentially capable of stabilizing highly unstable microbubbles (MBs) of air in aqueous solutions. The optimum system was butyl cyanoacrylate (BCA) polymerized into PBCA particles at pH 4 in the presence of 1 wt.% Tyloxapol surfactant.