Distribution and abundance of Aedes caspius (Pallas, 1771) and Aedes vexans (Meigen, 1830) in the Po Plain (northern Italy).

Background: Knowledge of the distribution and abundance of disease-causing mosquito vectors is fundamental for assessing the risk of disease circulation and introduction. Aedes caspius (Pallas, 1771) and Aedes vexans (Meigen, 1830) have been implicated, to different extents, in the circulation of several arthropod-borne viruses (arboviruses). These two mosquitoes are vectors of Tahyna virus in Europe and are considered potential vectors of Rift Valley fever virus, a virus not present but at risk of introduction on the continent.

Language-based game theory in the age of artificial intelligence.

Understanding human behaviour in decision problems and strategic interactions has wide-ranging applications in economics, psychology and artificial intelligence. Game theory offers a robust foundation for this understanding, based on the idea that individuals aim to maximize a utility function. However, the exact factors influencing strategy choices remain elusive.

Political ideology and generosity around the globe.

In a world severely put under stress by COVID-19, generosity becomes increasingly essential both when able to transcend local boundaries, building upon universalistic values, and when directed toward more local contexts, such as the native country. This study aims to investigate an underresearched determinant of generosity at these two levels, a factor that captures one's beliefs, values, and opinions about society: political ideology. We study the donation decisions of more than 46,000 participants from 68 countries in a task with the possibility of donating to a national charity and an international one.

Prosocial behavior in emergencies: Evidence from blood donors recruitment and retention during the COVID-19 pandemic.

The impact of COVID-19 represents a specific challenge for voluntary transfusional systems sustained by the intrinsic motivations of blood donors. In general, health emergencies can stimulate altruistic behaviors. However, in this context, the same prosocial motivations, besides the personal health risks, could foster the adherence to social distancing rules to preserve collective health and, therefore, discourage blood donation activities.

First report of two Asian invasive mosquito species, Aedes japonicus and Aedes koreicus, in Piedmont, northwest Italy.

Introduction: Aedes japonicus japonicus and Aedes koreicus are two invasive mosquitoes recently reported in various parts of Europe, including areas very close to Piedmont where, since 2012, specific tools have been implemented to allow the early detection of invasive mosquitoes, through the surveillance of the main points of entry.

Results: Thanks to the regional surveillance system, Ae. j.

Predicting attitudinal and behavioral responses to COVID-19 pandemic using machine learning.

At the beginning of 2020, COVID-19 became a global problem. Despite all the efforts to emphasize the relevance of preventive measures, not everyone adhered to them. Thus, learning more about the characteristics determining attitudinal and behavioral responses to the pandemic is crucial to improving future interventions.

Assessing the distribution of invasive Asian mosquitoes in Northern Italy and modelling the potential spread of Aedes koreicus in Europe.

In the last decade, Aedes koreicus and Aedes japonicus japonicus mosquitoes, which are competent vectors for various arboviruses of public health relevance, colonised Italy and other European countries. Nevertheless, information about their current and potential distribution is partial. Accordingly, in this study four regions of Northern Italy (Lombardy, Liguria, Piedmont and Aosta Valley) were surveyed during 2021 for the presence of eggs, larvae and pupae of these two invasive species.

National identity predicts public health support during a global pandemic.

Changing collective behaviour and supporting non-pharmaceutical interventions is an important component in mitigating virus transmission during a pandemic. In a large international collaboration (Study 1, N = 49,968 across 67 countries), we investigated self-reported factors associated with public health behaviours (e.g.

Mosquitoes of the Maculipennis complex in Northern Italy.

The correct identification of mosquito vectors is often hampered by the presence of morphologically indiscernible sibling species. The Maculipennis complex is one of these groups that include both malaria vectors of primary importance and species of low/negligible epidemiological relevance, of which distribution data in Italy are outdated. Our study was aimed at providing an updated distribution of Maculipennis complex in Northern Italy through the sampling and morphological/molecular identification of specimens from five regions.

Luminescent halogen-substituted 2-(N-arylimino)pyrrolyl boron complexes: the internal heavy-atom effect.

A group of new boron complexes [BPh{κN,N'-NCH-2-C(H)[double bond, length as m-dash]N-CHX}] (X = 4-Cl 4c, 4-Br 4d, 4-I 4e, 3-Br 4f, 2-Br 4g, 2-I 4h) containing different halogens as substituents in the N-aryl ring have been synthesized and characterized in terms of their molecular properties. Their photophysical characteristics have been thoroughly studied in order to understand whether these complexes exhibit an internal heavy-atom effect. Phosphorescence emission was found for some of the synthesized halogen-substituted boron molecules, particularly for 4g and 4h.

Boron complexes of aromatic 5-substituted iminopyrrolyl ligands: synthesis, structure, and luminescence properties.

A group of new mononuclear boron chelate compounds [BPh{κN,N'-5-R-NCH-2-C(H)[double bond, length as m-dash]N-Ar}] (R = Ar = CH7; R = CH, Ar = 2,6-iPrCH8; R = Anthracen-9-yl (Anthr), Ar = CH9; R = Anthr, Ar = 2,6-iPrCH10) were synthesized via the reaction of B(CH) with the corresponding 5-substituted 2-(N-arylformimino)pyrrole ligand precursors 3-6. These complexes were prepared in order to evaluate the luminescence potential derived from the substitution of the position 5 of the pyrrolyl ring with an aromatic group. Compounds 7-10 were photophysically characterized in solution and in the solid state.

Photophysical properties and biological evaluation of a Zinc(II)-5-methyl-1H-pyrazole Schiff base complex.

A new ZnL complex containing two molecules of a tridentate Schiff base derived from 5-methyl-1H-pyrazole (HL) is synthesized and characterized. The photophysical properties of HL and ZnL are disclosed and supported by CAMB3LYP DFT/TDDFT calculations. It is shown that there is keto-tautomer stabilization upon excitation with an energetically accessible triplet state in HL, not present in ZnL, this explaining the differences found in the emissions of the compounds.

Facts and Misconceptions about 2D:4D, Social and Risk Preferences.

We study how the ratio between the length of the second and fourth digit (2D:4D) correlates with choices in social and risk preferences elicitation tasks by building a large dataset from five experimental projects with more than 800 subjects. Our results confirm the recent literature that downplays the link between 2D:4D and many domains of economic interest, such as social and risk preferences. As for the former, we find that social preferences are significantly lower when 2D:4D is above the median value only for subjects with low cognitive ability.

Fluorescence Enhancement of a Cationic Fluorene-Phenylene Conjugated Polyelectrolyte Induced by Nonionic n-Alkyl Polyoxyethylene Surfactants.

The modulation of conjugated polyelectrolyte fluorescence response by nonionic surfactants is dependent on the structures of the surfactant and polymer, polymer average molecular weight, and polyelectrolyte-surfactant interactions. In this paper, we study the effect of nonionic n-alkyl polyoxyethylene surfactants (CE) with different alkyl chain lengths (CE with i = 6, 8, 10, and 12) and number of oxyethylene groups (CE with j = 5, 7, and 9) on the photophysics and ionic conductivity of poly{[9,9-bis(6'-N,N,N-trimethylammonium)-hexyl]-2,7-fluorene-alt-1,4-phenylene}bromide (HTMA-PFP) in dimethyl sulfoxide-water 4% (v/v). Molecular dynamics simulations show that HTMA-PFP chains tend to approach as the simulation evolves.

Luminescent Di- and Trinuclear Boron Complexes Based on Aromatic Iminopyrrolyl Spacer Ligands: Synthesis, Characterization, and Application in OLEDs.

New bis- and tris(iminopyrrole)-functionalized linear (1,2-(HNC4 H3 -C(H)N)2 -C6 H4 (2), 1,3-(HNC4 H3 -C(H)N)2 -C6 H4 (3), 1,4-(HNC4 H3 -C(H)N)2 -C6 H4 (4), 4,4'-(HNC4 H3 -C(H)N)2 -(C6 H4 -C6 H4 ) (5), 1,5-(HNC4 H3 C-(H)N)2 -C10 H6 (6), 2,6-(HNC4 H3 C-(H)N)2 -C10 H6 (7), 2,6-(HNC4 H3 C-(H)N)2 -C14 H8 (8)) and star-shaped (1,3,5-(HNC4 H3 -C(H)N-1,4-C6 H4 )3 -C6 H3 (9)) π-conjugated molecules were synthesized by the condensation reactions of 2-formylpyrrole (1) with several aromatic di- and triamines. The corresponding linear diboron chelate complexes (Ph2 B[1,3-bis(iminopyrrolyl)-phenyl]BPh2 (10), Ph2 B[1,4-bis(iminopyrrolyl)-phenyl]BPh2 (11), Ph2 B[4,4'-bis(iminopyrrolyl)-biphenyl]BPh2 (12), Ph2 B[1,5-bis(iminopyrrolyl)-naphthyl]BPh2 (13), Ph2 B[2,6-bis(iminopyrrolyl)-naphthyl]BPh2 (14), Ph2 B[2,6-bis(iminopyrrolyl)-anthracenyl]BPh2 (15)) and the star-shaped triboron complex ([4',4'',4'''-tris(iminopyrrolyl)-1,3,5-triphenylbenzene](BPh2 )3 (16)) were obtained in moderate to good yields, by the treatment of 3-9 with B(C6 H5 )3 . The ligand precursors are non-emissive, whereas most of their boron complexes are highly fluorescent; their emission color depends on the π-conjugation length.

Tunable fluorophores based on 2-(N-arylimino)pyrrolyl chelates of diphenylboron: synthesis, structure, photophysical characterization, and application in OLEDs.

Reactions of 2-(N-arylimino)pyrroles (HNC4H3C(H)=N-Ar) with triphenylboron (BPh3) in boiling toluene afford the respective highly emissive N,N'-boron chelate complexes, [BPh2 {κ(2)N,N'-NC4H3C(H)=N-Ar}] (Ar=C6H5 (12), 2,6-Me2-C6H3 (13), 2,6-iPr2-C6H3 (14), 4-OMe-C6H4 (15), 3,4-Me2-C6 H3 (16), 4-F-C6H4 (17), 4-NO2-C6H4 (18), 4-CN-C6H4 (19), 3,4,5-F3-C6H2 (20), and C6F5 (21)) in moderate to high yields. The photophysical properties of these new boron complexes largely depend on the substituents present on the aryl rings of their N-arylimino moieties. The complexes bearing electron-withdrawing aniline substituents 17-20 show more intense (e.

Model for conformational relaxation of flexible conjugated polymers: application to p-phenylenevinylene trimers in nonpolar solvents.

Photoexcitation of flexible conjugated polymers is invariably followed by a fast conformational/torsional relaxation towards a configuration favouring coplanarity of the conjugated segments. In general, the experimental relaxation rate constant (k(CR)) depends on the solvent viscosity (η) and temperature (T), and is not proportional to T/η. A theory capable of explaining the observed dependence of k(CR) on T and η over a wide range of these variables is not available.

Photophysical properties of iminopyrrolyl boron complexes: a DFT interpretation.

The three compounds [BPh(2)(κ(2)N,N'-NC(4)H(3)C(H)=N-C(6)H(5))] (A), [BPh(2)(κ(2)N,N'-NC(4)H(3)C(H)=N-1,4-C(6)H(4)-N=H)C-H(3)C(4)N-N,N'κ(2))BPh(2)] (B) and [BPh(2)(κ(2)N,N'-NC(4)H(3)C(H)=N-4,4'-C(6)H(4)-C(6)H(4)-N=(H)C-H(3)C(4)N-N,N'κ(2))BPh(2)] (C) are blue to green light emitters with average to excellent quantum yields. DFT and TD-DFT calculations were performed in order to understand their behaviour. The geometry of their ground and singlet excited state was optimised, and their absorption patterns and emission were calculated.

Syntheses and photophysical properties of new iminopyrrolyl boron complexes and their application in efficient single-layer non-doped OLEDs prepared by spin coating.

Efficient non-doped OLEDs have been achieved using new binuclear tetracoordinate organoboron complexes containing 2-(N-aryl)formiminopyrrolyl ligands.

How to change the aggregation in the DNA/surfactant/cationic conjugated polyelectrolyte system through the order of component addition: anionic versus neutral surfactants.

The competitive interaction has been studied between double-stranded DNA (dsDNA), the cationic conjugated polyelectrolyte (CPE) poly[9,9-bis(6-N,N,N-trimethylamonium)hexyl)-fluorene-phenylene)] bromide (HTMA-PFP) and anionic or neutral surfactants (sodium dodecyl sulfonate, SDSu, and n-dodecyl pentaoxyethylene glycol ether, C(12)E(5)) in 4% (v/v) dimethyl sulfoxide (DMSO)-water using UV/visible absorption and fluorescence spectroscopy. Dramatic changes are observed in the spectroscopic behavior of the system depending on the order of addition of the reagents, the surfactant charge, and concentration range. If the neutral C(12)E(5) is added to the HTMA-PFP/dsDNA complex, no significant spectroscopic changes are observed.

Synthesis, structure, and photophysical characterization of blue-green luminescent zinc complexes containing 2-iminophenanthropyrrolyl ligands.

New 2-iminophenanthro[9,10-c]pyrrole ligand precursors containing phenyl or 2,6-diisopropylphenyl groups at the imine nitrogen substituent, 2-arylformiminophenanthro[9,10-c]pyrroles (aryl = phenyl IIa, 2,6-diisopropylphenyl IIb) were synthesized and deprotonated in situ with NaH, originating solutions of the corresponding sodium salts (IVa, IVb). The reaction of these salts with zinc chloride gave the homoleptic bis-ligand Zn(II) complexes [Zn(kappa(2)N,N'-2-arylformiminophenanthro[9,10-c]pyrrolyl)(2)] (aryl = phenyl 2a, 2,6-diisopropylphenyl 2b). The new ligand precursors and complexes were characterized by NMR, elemental analysis, UV/vis spectroscopy, and X-ray crystallography, when possible.

Interaction between poly(9,9-bis(6'-N,N,N-trimethylammonium)hexyl)fluorene phenylene bromide and DNA as seen by spectroscopy, viscosity, and conductivity: effect of molecular weights and DNA secondary structure.

The interaction between three poly(9,9-bis(6-N,N,N-trimethylammonium)hexyl)fluorene phenylene) bromide (HTMA-PFP) samples of different molecular weights (Mn=14.5, 30.1 and 61.

Photodynamics of a PV trimer in high-viscosity solvents and in PMMA films: a new insight into energy transfer versus conformational relaxation in conjugated polymers.

Non-Stokes-Einstein relaxation: The rate constant of conformational relaxation of a phenylenevinylene trimer (see picture) in different solvents is proportional to eta(-alpha), with alpha values decreasing from close to unity (low viscosity) to zero at sufficiently high solvent viscosity. This behaviour is attributed to the flexible methylbutyl side chains of the trimer, which partially screen the solvent friction. The p-phenylenevinylene (PV) trimer (MBOPV3) was used to probe the effect of conformational relaxation on fluorescence decays of PV-based polymers in the high solvent viscosity regime, from n-hexadecane (3.