Publications by authors named "Paolo Andrich"

Article Synopsis
  • Carbon nanodots (CNDs) are innovative light-harvesters that have potential use as efficient photosensitizers in photocatalytic reactions, but their charge carrier dynamics are not fully understood.
  • This study focuses on nitrogen-doped graphitic CNDs (NgCNDs), examining their interactions with methyl viologen (MV) and varying electron donors (EDs) like ascorbic acid (AA) and ethylenediaminetetraacetic acid (EDTA) to investigate the formation of the MV radical cation.
  • Findings reveal different quenching mechanisms based on the ED used, highlighting that AA causes rapid oxidative quenching while EDTA leads to slower reductive quenching, offering
View Article and Find Full Text PDF

Excitonic insulators host a condensate of electron-hole pairs at equilibrium, giving rise to collective many-body effects. Although several materials have emerged as excitonic insulator candidates, evidence of long-range coherence is lacking and the origin of the ordered phase in these systems remains controversial. Here, using ultrafast pump-probe microscopy, we investigate the possible excitonic insulator TaNiSe Below 328 K, we observe the anomalous micrometer-scale propagation of coherent modes at velocities of ~10 m/s, which we attribute to the hybridization between phonon modes and the phase mode of the condensate.

View Article and Find Full Text PDF

The layered chalcogenide TaNiSe has been proposed to host an excitonic condensate in its ground state, a phase that could offer a unique platform to study and manipulate many-body states at room temperature. However, identifying the dominant microscopic contribution to the observed spontaneous symmetry breaking remains challenging, perpetuating the debate over the ground state properties. Here, using broadband ultrafast spectroscopy we investigate the out-of-equilibrium dynamics of TaNiSe and demonstrate that the transient reflectivity in the near-infrared range is connected to the system's low-energy physics.

View Article and Find Full Text PDF

Temperature sensors with micro- and nanoscale spatial resolution have long been explored for their potential to investigate the details of physical systems at an unprecedented scale. In particular, the rapid miniaturization of transistor technology, with its associated steep boost in power density, calls for sensors that accurately monitor heating distributions. Here, we report on a simple and scalable fabrication approach, based on directed self-assembly and transfer-printing techniques, to constructing arrays of nanodiamonds containing temperature-sensitive fluorescent spin defects.

View Article and Find Full Text PDF

The elimination of defects from SiC has facilitated its move to the forefront of the optoelectronics and power-electronics industries. Nonetheless, because certain SiC defects have electronic states with sharp optical and spin transitions, they are increasingly recognized as a platform for quantum information and nanoscale sensing. Here, we show that individual electron spins in high-purity monocrystalline 4H-SiC can be isolated and coherently controlled.

View Article and Find Full Text PDF

The nitrogen-vacancy (NV) center in diamond is an attractive platform for quantum information and sensing applications because of its room temperature operation and optical addressability. A major research effort focuses on improving the quantum coherence of this defect in engineered micro- and nanoscale diamond particles (DPs), which could prove useful for high-resolution sensing in fluidic environments. In this work we fabricate cylindrical diamonds particles with finely tuned and highly reproducible sizes (diameter and height ranging from 100 to 700 and 500 nm to 2 μm, respectively) using high-purity, single-crystal diamond membranes with shallow-doped NV centers.

View Article and Find Full Text PDF