Enhancement of Sm Luminescence in Sol-Gel Silica Matrix: Effect of Ligands Phenyl Phosphinic Acid and Trioctylphosphine Oxide.

Sol-gel silica matrices singly doped with Sm and co-doped with ligands phenyl phosphinic acid (PPIA) and trioctylphosphine oxide (TOPO) were fabricated and studied for their structural and spectroscopic behaviour. Structural studies were done by x-ray diffraction (XRD) and Fourier transform infra-red (FTIR) absorption analysis whereas spectroscopic behaviour was studied by ultraviolet - visible (UV-Vis) absorption, photoluminescence (PL) excitation, emission and time-correlated decay analyses. XRD studies exhibit the amorphous nature of the samples and FTIR studies corroborate the presence of the ligands in the silica matrix.

Design, Synthesis, Biological Evaluation and in Silico Studies of Curcumin Pyrrole Conjugates.

Curcumin conjugated heterocyclic compounds are potent candidates with drug likeness against various bacterial pathogens. A set of curcumin-based pyrrole conjugates (CPs) were synthesized and characterized by FT-IR, H and C NMR and HR-MS techniques. The results of free radical scavenging activity of the synthesized CPs, evaluated by FRAP and CUPRAC assays, showed the potency of these compounds as effective antioxidants.

Blockchain technology in supply chain operations: Applications, challenges and research opportunities.

Blockchain is a technology with unique combination of features such as decentralized structure, distributed notes and storage mechanism, consensus algorithm, smart contracting, and asymmetric encryption to ensure network security, transparency and visibility. Blockchain has immense potential to transform supply chain (SC) functions, from SC provenance, business process reengineering to security enhancement. More and more studies exploring the use of blockchain in SCs have appeared in recent years.