The occurrence of Potentially Toxic Elements (PTEs) and other chemical elements in urban and peri-urban soils impacts human health and quality of life, posing a challenge for geoscientists. This study investigated the soil geochemistry of Lamia City, focusing on identifying the geogenic and anthropogenic origins of elements. A total of 168 topsoil samples (0-10 cm) were collected in April 2023, and the analysis included the near-total concentrations of 51 elements.
View Article and Find Full Text PDFThe occurrence, mobilization, and origin of Potentially Toxic Eelements (PTEs) in the environment is always a difficult research question that has not been fully addressed to date; solving this problem would be a major achievement for environmental science and pollution research, a significant scientific breakthrough, and an important contribution to environmental analysis and monitoring. The lack of a holistic methodology that uses chemical analysis to determine the origin of each PTE in the environment is the main motivation for this project. Therefore, the hypothesis tested here is to develop a scientific approach applied to each PTE to determine whether its origin is geogenic (i.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
September 2021
A scientometric analysis based on the Scopus database was conducted to provide insight into research activities on the occurrence of potentially toxic elements (PTEs) (As, Cd, Co, Cr, Cu, Hg, Ni, Pb, Sb, and Zn) in groundwater during 1970-2019. The selection of these PTEs was based on their significance concerning their reference frequency in environmental science and pollution research (ESPR) studies and their toxicity to living organisms. The analysis utilizes data about the quantity, type, journal, geographical, institutional, and funding patterns of publications.
View Article and Find Full Text PDFThe aim of this paper is to provide a methodology including statistical tools and spatial techniques, in order to identify the various potential sources of chromium (Cr) in the Sarigkiol basin, Western Macedonia, Greece, where elevated concentrations of Cr in groundwater have been recorded since 1996. Integrated hydrochemical approach and statistical analyses including Pearson's correlation coefficient, multivariate statistical analyses (factor analysis and hierarchical cluster analysis), and spatial techniques (Moran's I spatial autocorrelation index and bivariate local indicator spatial association cluster map) were applied to evaluate the chemical analyses of 73 water samples, from irrigation wells, natural springs, and surface water. Both natural and anthropogenic sources of Cr were recorded; the first (ultramafic-dominated environment) is strongly depicted on the natural spring water, in which Cr concentrations as high as ~ 130 μg/L were recorded, whereas the second (agricultural activities) acts synergistically in the irrigation wells of the Sarigkiol basin, in which strong correlations of Cr, P, and NO were defined.
View Article and Find Full Text PDFIn the present study, we approach the geochemical processes affecting the hydrochemistry and resulting in elevated concentrations of hexavalent chromium (Cr) in groundwater of the Psachna basin, central Euboea, Greece. Sixty-five groundwater samples and 16 topsoil (5-20 cm) samples were studied in order to examine groundwater and soil quality in relation to geogenic processes and anthropogenic activities. Specifically, the origin of Cr and Cr in groundwater was investigated by co-evaluating (a) hydrochemical cross plots of major ions; (b) spatial distribution maps of Cl, Mg, NO, and Cr; (c) multivariate statistical analyses such as factor analysis (FA) and hierarchical cluster analysis (HCA) of groundwater geochemistry; (d) chemical analyses of soil samples; and (e) chemical analyses of fertilizers.
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