Topology sorting: Separating linear/star polymer blend components by imbibition in nanopores.

We report the imbibition and adsorption kinetics of a series of symmetric linear/star cis-1,4-polyisoprene blends within the long channels of self-ordered nanoporous anodic aluminum oxide (abbreviated: AAO). Using in situ nanodielectric spectroscopy, we followed the evolution of the longest chain modes in the blends with a judicious selection of molar masses for the constituent components. We demonstrated differences in the imbibition kinetics of linear and star components based on the relative viscosities (e.

A Terrylene-Anthraquinone Dyad as a Chromophore for Photothermal Therapy in the NIR-II Window.

A terrylenedicarboximide-anthraquinone dyad, , with absorption in the second near-infrared region (NIR-II) is obtained as a high-performance chromophore for photothermal therapy (PTT). The synthetic route proceeds by C-N coupling of amino-substituted terrylenedicarboximide (TMI) and 1,4-dichloroanthraquinone followed by alkaline-promoted dehydrocyclization. with extended π-conjugation exhibits an optical absorption band peaking at 1140 nm and extending into the 1500 nm range.

Non-equilibrium Effects of Polymer Dynamics under Nanometer Confinement: Effects of Architecture and Molar Mass.

The non-equilibrium dynamics of linear and star-shaped -1,4 polyisoprenes confined within nanoporous alumina is explored as a function of pore size, , molar mass, and functionality ( = 2, 6, and 64). Two thermal protocols are tested: one resembling a quasi-static process (I) and another involving fast cooling followed by annealing (II). Although both protocols give identical equilibrium times, it is through protocol I that it is easier to extract the equilibrium times, , by the linear relationships of the characteristic peak frequencies with time and rate, respectively, as log(f) = - log() and log(f) = + λ log(β).

Layers of Distinct Mobility in Densely Grafted Dendrimer Arborescent Polymer Hybrids.

Melts of multiarm stars of 1,4-polybutadiene (dendrimer arborescent hybrids) with very high branching functionality (f) and small arm molar mass behave as jammed colloids and show distinct layers of segmental mobility. Three mobility layers were identified, comprising outer, intermediate, and near-core segments, all displaying a Vogel-Fulcher-Tammann temperature dependence. The respective glass temperatures increase as f^{1/2}.