Synthesis, crystal structure and Hirshfeld and thermal analysis of bis[benzyl 2-(heptan-4-yl-idene)hydrazine-1-carboxyl-ate-κ ,]bis(thio-cyanato)-nickel(II).

The title centrosymmetric Ni complex, [Ni(NCS)(CHNO)], crystallizes with one half mol-ecule in the asymmetric unit of the monoclinic unit cell. The complex adopts an octa-hedral coordination geometry with two mutually benzyl-2-(heptan-4-yl-idene)hydrazine-1-carboxyl-ate ligands in the equatorial plane with the axial positions occupied by N-bound thio-cyanato ligands. The overall conformation of the mol-ecule is also affected by two, inversion-related, intra-molecular C-H⋯O hydrogen bonds.

New cobalt(II) and nickel(II) complexes of benzyl carbazate Schiff bases: Syntheses, crystal structures, in vitro DNA and HSA binding studies.

In the present study, new Schiff base complexes with the composition [M(NCS)(L1)]·nHO, where M=Co (n=0) (1) and Ni (n=2) (2); [M(NCS)(L2)], M=Co (3) and Ni (4) as well as [M(NCS)(L3)], M=Co (5) and Ni (6); (L1=benzyl 2-(propan-2-ylidene)hydrazinecarboxylate, L2=benzyl 2-(butan-2-ylidene)hydrazinecarboxylate and L3=benzyl 2-(pentan-3-ylidene)hydrazinecarboxylate) have been synthesized by a template method. The complexes were characterised by analytical methods, spectroscopic studies, thermal and X-ray diffraction techniques. The structures of all the complexes explore that the metal(II) cation has a trans-planar coordination environment, the monomeric units containing a six-coordinated metal center in octahedral geometry with N-bound isothiocyanate anions coordinated as terminal ligands.