Deposition of Nanometric Polymer-Surfactant Complexes Formed by Cationic Dextran: A Path to Sustainable Formulations.

The home and personal care industry is evolving toward more sustainable and environmentally friendly ingredients. Rinse-off personal care products rely on formation of polymer-surfactant complexes to drive deposition of benefit agents (e.g.

Helical Luttinger Liquid on a Space-Time Lattice.

The Luttinger model is a paradigm for the breakdown due to interactions of the Fermi liquid description of one-dimensional massless Dirac fermions. Attempts to discretize the model on a one-dimensional lattice have failed to reproduce the established bosonization results because of the fermion-doubling obstruction: a local and symmetry-preserving discretization of the Hamiltonian introduces a spurious second species of low-energy excitations, while a nonlocal discretization opens a single-particle gap at the Dirac point. Here, we show how to work around this obstruction by discretizing both space and time to obtain a local Lagrangian for a helical Luttinger liquid with Hubbard interaction.

Impact of Degree of Ethoxylation on Sodium Lauryl Ether Sulfate Surfactant Adsorption onto Silicone-in-Water Emulsion Droplets.

Silicone-in-water emulsions have found widespread use as lubricants, water repellants, softeners, binders, antiblocking agents, antislip agents, and defoamers across a diverse range of markets including textiles, coatings, pharmaceuticals, and home and personal care. Stable incorporation of silicone emulsions into formulated products for these applications can be a challenge. This study seeks to enable formulation by investigating the impact of the degree of ethoxylation of sodium lauryl ether sulfate (SLES) surfactants on their ability to displace surfactant stabilizer at the silicone-water interfaces of polydimethylsiloxane (PDMS)-in-water emulsion droplets.

Designing Multicomponent Polymer Colloids for Self-Stratifying Films.

Aqueous polymer colloids known as latexes are widely used in coating applications. Multicomponent latexes comprised of two incompatible polymeric species organized into a core-shell particle morphology are a promising system for self-stratifying coatings that spontaneously partition into multiple layers, thereby yielding complex structured coatings requiring only a single application step. Developing new materials for self-stratifying coatings requires a clear understanding of the thermodynamic and kinetic properties governing phase separation and polymeric species transport.

Reflectionless Klein tunneling of Dirac fermions: comparison of split-operator and staggered-lattice discretization of the Dirac equation.

Massless Dirac fermions in an electric field propagate along the field lines without backscattering, due to the combination of spin-momentum locking and spin conservation. This phenomenon, known as 'Klein tunneling', may be lost if the Dirac equation is discretized in space and time, because of scattering between multiple Dirac cones in the Brillouin zone. To avoid this, a staggered space-time lattice discretization has been developed in the literature, withsingle Dirac cone in the Brillouin zone of the original square lattice.

Effects of exposure to air pollution on acute cardiovascular and respiratory admissions to the hospital and early mortality at emergency department.

Background: Particulate matter (PM) and NO2 induce pathophysiological changes which contribute to an increased incidence of acute cardiovascular (CV) and respiratory (Rp) events.

Objectives: To analyze the relationship between air quality and the frequency of admissions to the emergency department (ED) due to the CV diseases and Rp causes.

Material And Methods: The study analyzed the reasons for admissions to the ED during the cold periods from January 2017 to January 2020.

Deconfinement of Majorana Vortex Modes Produces a Superconducting Landau Level.

A spatially oscillating pair potential Δ(r)=Δ_{0}e^{2iK·r} with momentum K>Δ_{0}/ℏv drives a deconfinement transition of the Majorana bound states in the vortex cores of a Fu-Kane heterostructure (a 3D topological insulator with Fermi velocity v, on a superconducting substrate with gap Δ_{0}, in a perpendicular magnetic field). In the deconfined phase at zero chemical potential the Majorana fermions form a dispersionless Landau level, protected by chiral symmetry against broadening due to vortex scattering. The coherent superposition of electrons and holes in the Majorana Landau level is detectable as a local density of states oscillation with wave vector sqrt[K^{2}-(Δ_{0}/ℏv)^{2}].

Implementation of the European Psychiatric Association (EPA) guidance on forensic psychiatry in Poland. Current state and required measures.

The article discusses the key aspects of the guidance of the European Psychiatric Association (EPA) on forensic psychiatry and the required actions to implement guidance into clinical practice. The authors pay attention to the discrepancies between the recommendations resulting from the guidance and clinical practice and current systemic solutions. The basic difficulties were discussed in relation to the implementation of the guidelines in the clinical practice in Poland as regards providing services as an expert by psychiatrists and psychologists, risk assessment and management, psychiatric therapy in detention centers, implementation of protection measures in inpatient and outpatient treatment conditions, efficiency of pharmacological and non-pharmacological interventions.

Tractography-guided surgery of brain tumours: what is the best method to outline the corticospinal tract?

Background: Diffusion tensor imaging (DTI) is the imaging technique used in vivo to visualise white matter pathways. The cortico-spinal tract (CST) belongs to one of the most often delineated tracts preoperatively, although the optimal DTI method has not been established yet. Considering that various regions of interests (ROIs) could be selected, the reproducibility of CST tracking among different centres is low.

Reliability of diffusion tensor tractography of facial nerve in cerebello-pontine angle tumours.

Aim Of The Study: This study aimed to verify the accuracy of preoperative visualisation of the facial nerve (FN) by magnetic resonance-based (MR) diffusion tensor imaging-fibre tracking (DTI-FT) with neuronavigation system integration in patients with cerebello-pontine angle (CPA) tumours.

Clinical Rationale For The Study: Complete excision with preservation of the FN remains the critical goal of today's vestibular schwannoma (VS) surgery. DTI-FT of the FN with neuronavigation is yet to be fully evaluated, and could make surgery safer.

Topologically Protected Landau Level in the Vortex Lattice of a Weyl Superconductor.

The question whether the mixed phase of a gapless superconductor can support a Landau level is a celebrated problem in the context of d-wave superconductivity, with a negative answer: the scattering of the subgap excitations (massless Dirac fermions) by the vortex lattice obscures the Landau level quantization. Here we show that the same question has a positive answer for a Weyl superconductor: the chirality of the Weyl fermions protects the zeroth Landau level by means of a topological index theorem. As a result, the heat conductance parallel to the magnetic field has the universal value G=1/2g_{0}Φ/Φ_{0}, with Φ as the magnetic flux through the system, Φ_{0} as the superconducting flux quantum, and g_{0} as the thermal conductance quantum.

[Children sexual abuse in Poland--study of 257 sexual offenders against minors].

Introduction: Obtaining objective data on sexual offenders against minors is difficult. In order to enhance the possibilities to prevent such crimes it is essential to determine factors that condition this kind of sexual behavior.

Aim: The aim of the study was to prepare a multidimensional analysis of a profile of sexual offenders against minors.

Research nurses collaborate with clinical nurses for success in the National Children's Study.

The National Children's Study is a longitudinal, prospective, observational study designed to enroll more than 100,000 children from more than 100 communities across the United States. In this article, research nurses share their experiences as members of one Vanguard Study Center in the planning, development, and implementation of tailored research protocols. Collaboration among research and clinical nurses and use of the RN birth team model were critical for success.

Static time-of-flight secondary ion mass spectrometry imaging of freeze-fractured, frozen-hydrated biological membranes.

The study of cell membrane lipid and steroid composition and distribution is important for the understanding of membrane dynamics and function. Here we present efforts to chemically image phospholipid distributions on a submicron scale on freeze-fractured and frozen-hydrated liposomes and red blood cells using time-of-flight secondary ion mass spectrometry. Sample preparation by freeze fracturing of membranes is described.

Atomic and molecular imaging at the single-cell level with TOF-SIMS.

A complete cold chain freeze-fracture methodology has been developed to test the feasibility of using time-of-flight secondary ion mass spectrometry (TOF-SIMS) imaging for the molecular analysis of frozen hydrated biological samples. Because the technique only samples the first few monolayers of a sample, water on the surface of a sample can be a major source of interference. This problem can be minimized by placing a cold trap (fracture knife and housing at -196 degrees C) near the fractured sample that is held at a warmer temperature (-97 to -113 degrees C).

Changes in intracellular sodium during the hydroosmotic response to vasopressin.

During vasopressin (VP)-induced water movement, toad urinary bladder epithelial cells undergo unique morphological changes. The osmolality within these responding cells remains relatively stable despite the large transcellular transport of water. We hypothesized that the hydroosmotic response to VP may be associated with a net increase in sodium either as an aid in maintaining the intracellular osmolality or as part of a Na-Ca exchange process.

Time-dependent aldosterone metabolism in toad urinary bladder.

Aldosterone (Aldo) metabolism was examined in the toad bladder. Bladders were incubated with [3H]aldosterone (10(-7) M) for 5 h, 1 h, or 10 min. Tissues were analyzed for metabolites using high-pressure liquid chromatography (HPLC).

Fluctuations in intracellular pH associated with vasopressin stimulation.

Intracellular pH (pHi) was estimated in paired hemibladders isolated from Dominican toads (Bufo marinus) by the tissue distribution of [14C]5,5'-dimethyl-2,4-oxazolidinedione and [3H]inulin. Tissues were incubated with isotopes for 30 min to correlate changes in pHi with the approximate time of peak vasopressin (VP)-induced water flow. At serosal pH 7.

Mineralocorticoid activity of 19-hydroxyaldosterone, 19-nor-aldosterone, and 3 beta-hydroxy-delta 5-aldosterone: relative potencies measured in two bioassay systems.

The mineralocorticoid (MC) activities of 19-hydroxyaldosterone (19-OH-Aldo) and 19-nor-aldosterone (19-nor-Aldo) were tested in adrenalectomized male rats. Potency was assessed by three criteria. Overall MC activity is expressed as the ability to decrease the urinary Na+ to K+ ratio; antinatriuretic activity is represented by decreases in the urinary Na+ to creatinine ratio, and kaliuretic activity by increases in the K+ to creatinine ratio.

The effects of antimineralocorticoids on synthesis of aldosterone metabolites in target tissues.

[3H]Aldosterone is transformed into several metabolites by subcellular fractions of rat kidney. 80-90% of the metabolites synthesized by nuclei and plasma membranes are 5 alpha-DHAldo and 3 alpha,5 alpha-THAldo in ratios of 1:2 and 1:1 respectively; small quantities of 3 beta,5 alpha-THAldo are also synthesized. In contrast, kidney cytosol metabolizes Aldo principally to 5 beta-reduced products with co-chromatograph with 5 beta-DHAldo and 3 alpha,5 beta-THAldo.

Effects of bilirubin on transepithelial transport of sodium, water, and urea.

Urinary concentrating defects and renal salt wasting have been described in the hyperbilirubinemic Gunn strain strain of rat. Homozygous animals demonstrate significant reductions in renal medullary urea and sodium ion concentrations. These observations are consistent with possible bilirubin associated disorders in the transepithelial transport of water and solute.