Dynamical mechanisms leading to equilibration in two-component gases.

Demonstrating how microscopic dynamics cause large systems to approach thermal equilibrium remains an elusive, longstanding, and actively pursued goal of statistical mechanics. We identify here a dynamical mechanism for thermalization in a general class of two-component dynamical Lorentz gases and prove that each component, even when maintained in a nonequilibrium state itself, can drive the other to a thermal state with a well-defined effective temperature.

Extensions of effective-medium theory of transport in disordered systems.

The effective-medium theory of transport in disordered systems, whose basis is the replacement of spatial disorder by temporal memory, is extended in several practical directions. Restricting attention to a one-dimensional system with bond disorder for specificity, a transformation procedure is developed to deduce explicit expressions for the memory functions from given distribution functions characterizing the system disorder. It is shown how to use the memory functions in the Laplace domain forms in which they first appear, and in the time domain forms which are obtained via numerical inversion algorithms, to address time evolution of the system beyond the asymptotic domain of large times normally treated.

Random-walk access times on partially disordered complex networks: an effective medium theory.

An analytic effective medium theory is constructed to study the mean access times for random walks on hybrid disordered structures formed by embedding complex networks into regular lattices, considering transition rates F that are different for steps across lattice bonds from the rates f across network shortcuts. The theory is developed for structures with arbitrary shortcut distributions and applied to a class of partially disordered traversal enhanced networks in which shortcuts of fixed length are distributed randomly with finite probability. Numerical simulations are found to be in excellent agreement with predictions of the effective medium theory on all aspects addressed by the latter.

Variational formula for the relaxation time in the Boltzmann equation.

The relaxation time approximation (RTA) is commonly employed in nonequilibrium statistical mechanics to approximate solutions to the Boltzmann equation in terms of an exponential relaxation to equilibrium. Despite its common use, the RTA suffers from the drawback that relaxation times commonly employed are independent of initial conditions. We derive a variational principle for solutions to the Boltzmann equation, which allows us to extend the standard RTA using relaxation times that depend on the initial distribution.

Traversal times for random walks on small-world networks.

We study the mean traversal time for a class of random walks on Newman-Watts small-world networks, in which steps around the edge of the network occur with a transition rate that is different from the rate for steps across small-world connections. When f>>F, the mean time to traverse the network exhibits a transition associated with percolation of the random graph (i.e.

Static pairwise annihilation in complex networks.

We study static annihilation on complex networks, in which pairs of connected particles annihilate at a constant rate during time. Through a mean-field formalism, we compute the temporal evolution of the distribution of surviving sites with an arbitrary number of connections. This general formalism, which is exact for disordered networks, is applied to Kronecker, Erdös-Rényi (i.

Nature of charge carriers in disordered molecular solids: are polarons compatible with observations?

Polaronic theories for charge transport in disordered organic solids, particularly molecularly doped polymers, have been plagued by issues of internal consistency related to the magnitude of physical parameters. We present a natural resolution of the problem by showing that, in the presence of correlated disorder, polaronic carriers with binding energies Delta approximately 50-500 meV and transfer integrals J approximately 1-20 meV are completely consistent with the magnitudes of field and temperature dependent mobilities observed.