X-ray computed tomography of holographically fabricated three-dimensional photonic crystals.

X-ray computed tomography is used to reconstruct the 3D structure of a polymeric photonic crystal. The reconstructed structure is compared to the structure predicted by a model. This analysis provides means to better understand deformations that occur during holographic fabrication of photonic crystals.

Epitaxial growth of three-dimensionally architectured optoelectronic devices.

Optoelectronic devices have long benefited from structuring in multiple dimensions on microscopic length scales. However, preserving crystal epitaxy, a general necessity for good optoelectronic properties, while imparting a complex three-dimensional structure remains a significant challenge. Three-dimensional (3D) photonic crystals are one class of materials where epitaxy of 3D structures would enable new functionalities.

Inverse design for phase mask lithography.

We have developed a method for designing the diffractive optics used in phase mask lithography. Genetic algorithms were used to inverse-design a grating's relief profile and associated exposure conditions so that desired periodic structures are formed. An experimentally promising grating designed to produce helices is demonstrated.

DNA and DNAzyme-mediated 2D colloidal assembly.

DNA-mediated interactions present a significant opportunity for controlling colloidal self-assembly. Using microcontact printing to achieve spatial control of DNA-surface patterning and DNA-functionalized polystyrene colloids, we report that DNA hybridization can be utilized for sequence-specific reversible self-assembly of well-ordered 2D colloidal arrays. Two essential indicators of DNA-hybridization mediated assembly were confirmed: thermal reversibility and sequence specificity.

Photopolymer-filled nanoporous glass as a dimensionally stable holographic recording medium.

The holographic recording characteristics of a photopolymer-nanoporous-glass composite are reported. An M/# of 3.2 is measured in this medium by angle multiplexing of a series of plane-wave holograms.