Foodborne pathogens, food adulterants, allergens, and toxic chemicals in food can cause major health hazards to humans and animals. Stringent quality control measures at all stages of food processing are required to ensure food safety. There is, therefore, a global need for affordable, reliable, and rapid tests that can be conducted at different process steps and processing sites, spanning the range from the sourcing of food to the end-product acquired by the consumer.
View Article and Find Full Text PDFIn this piece of work, microwave-assisted conversion of a natural precursor in to high-valued nano-scale material was carried out by a completely greener method. The fluorescent carbon dots prepared, designated as long pepper derived carbon dots (LPCDs), have been thoroughly characterized to explore the physical and chemical properties. The system exhibits excitation dependent emission behavior and from the optimal studies the excitation and emission wavelength of the system was found to be 330 nm and 455 nm respectively.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
February 2023
Herein, we report an eco-friendly biomass based completely greener microwave assisted synthesis of carbon dots from wild lemon leaves having superior photo-luminescent properties with moderately good quantum yield. The carbon dots synthesized (LLCDs) were characterized by high resolution transmission electron microscopy, fluorescent, UV-vis absorption, Fourier transform infrared and Raman spectroscopic techniques. The quenching of native fluorescence of LLCDs observed with tetracycline antibiotic was made use to make it as a fluorescent probe.
View Article and Find Full Text PDFFive new mononuclear lanthanide complexes, [LnL][EtNH]·THF/HO (Ln = Nd, Tb, Dy) (HL = 2-bis(2-hydroxy-3,5-dichloro benzyl)aminomethyl]pyridine), Ln = Nd (), Tb (), and Dy (), and (HL = 2-bis(2-hydroxy-3,5-dibromo benzyl)aminomethyl]pyridine), Ln = Nd (, HO) and Tb (), were synthesized and structurally characterized by single-crystal X-ray diffraction analyses. Being isostructural in all the five cases, the metal center is octa-coordinated with a triangular dodecahedron ( symmetry) geometry, and it is independent of the halogen substitution (Cl/Br). This close similarity is due to the composite interplay of hydrogen/halogen bond interactions that control the overall crystal packing, yet notable differences in association patterns among the individual ones arise from the subtle stereo-electronic requirement of individual molecules in the three-dimensional (3D) architecture.
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