The introduction of heterovalent metal ion doping in the lead (Pb) halide perovskites presents a novel opportunity to manipulate the electronic and ionic properties by introducing dopant charges and increasing the carrier concentration in single crystals. While previous studies have reported on the use of bismuth (Bi) doping in methylammonium lead tribromide (MAPbBr) to adjust the optical properties, the comprehensive impact of Bi doping on the structural and electronic properties of MAPbBr single crystals remains unexplored. This research, therefore, delves into the anomalous behavior of the structural, optical, and electrical properties of pristine and doped MAPbBr single crystals through a combination of experimental and computational studies.
View Article and Find Full Text PDFBackground: A 63-year-old Black woman presented with progressive exertional dyspnea and chronic lower back pain. The course and findings in her case are instructive.
Case Report: Family history was notable for cardiac deaths.
Rising oncology healthcare costs have led to value-based care reimbursement models that coordinate care and improve quality while reducing overall spending. These models are increasingly important for traditional Medicare and other payers. To compare the incidence of adverse events (AEs), AE-associated excess costs, and total cost of care (TCOC) of 3 cohorts receiving first-line treatment for metastatic pancreatic ductal adenocarcinoma (mPDAC).
View Article and Find Full Text PDFThe Unified Power Quality Conditioner (UPQC) is a promising solution for mitigating multiple Power Quality(PQ) issues in distribution systems, including harmonics, poor power factor, voltage sag/swell and voltage imbalance. The conventional Sliding Mode Controller (SMC) in UPQCs suffers from wide switching frequency variations, chattering problems, and inherent active and reactive power coupling. This study proposes a nonlinear control method, Sliding Mode-based Direct Power Control (SMC-DPC), for the simultaneous regulation of the shunt and series compensators in a UPQC.
View Article and Find Full Text PDFMYB proteins are ubiquitous in nature, regulating key aspects of plant growth and development. Although MYB proteins are known for regulating genes involved in secondary metabolite biosynthesis, particularly phenylpropanoids, their roles in terpenoid, glucosinolate, and alkaloid biosynthesis remain less understood. This review explores the structural and functional differences between activator and repressor MYB proteins along with their roles in plant growth, development, stress responses, and secondary metabolite production.
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