Towards a unified fold-cusp model for bond polarity scaling: electron rearrangements in the pyrolytic isomerization of cubane to cyclooctatetraene.

Context: This study meticulously examines the criteria for assigning electron rearrangements along the intrinsic reaction coordinate (IRC) leading to bond formation and breaking processes during the pyrolytic isomerization of cubane (CUB) to 1,3,5,7-cyclooctatetraene (COT) from both thermochemical and bonding perspectives. Notably, no cusp-type function was detected in the initial thermal conversion step of CUB to bicyclo[4.2.

Safety After Dark: A Privacy Compliant and Real-Time Edge Computing Intelligent Video Analytics for Safer Public Transportation.

Public transportation systems play a vital role in modern cities, but they face growing security challenges, particularly related to incidents of violence. Detecting and responding to violence in real time is crucial for ensuring passenger safety and the smooth operation of these transport networks. To address this issue, we propose an advanced artificial intelligence (AI) solution for identifying unsafe behaviours in public transport.

Changes in Availability and Affordability on the University Food Environment: The Potential Influence of the COVID-19 Pandemic.

Background: The COVID-19 pandemic has had an impact on the eating habits of the general population, among other reasons, because it has affected access to commercial establishments since some of them closed. This study aimed to describe potential changes that occurred between 2019 and 2022 in the availability and affordability of food and beverages in the food environment of a Brazilian public university.

Methods: Cross-sectional and descriptive study conducted at a public university located in Rio de Janeiro, Brazil.

Copper and Silver Trispyrazolylborate-Phosphinoazide Complexes: Synthesis, Characterization, and Nitrene Generation.

Phosphinoazide complexes of the composition TpM-L (M = Cu, Ag, and L = 2-azido-1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1-1,3,2-diazaphosphole) have been synthesized and structurally characterized. Their thermal decomposition led to cyclodiphosphazenes as a result of the metal-mediated coupling of two nitrene units in a process that takes place in both a stoichiometric and catalytic manner. Experimental data have allowed proposing a mechanistic pathway for this new transformation.