Publications by authors named "P Kielty"

Event cameras contain emerging, neuromorphic vision sensors that capture local-light​ intensity changes at each pixel, generating a stream of asynchronous events. This way of acquiring visual information constitutes a departure from traditional frame-based cameras and offers several significant advantages - low energy consumption, high temporal resolution, high dynamic range and low latency. Driver monitoring systems (DMS) are in-cabin safety systems designed to sense and understand a drivers physical and cognitive state.

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Ring-fused benzimidazolequinones are well-known anti-tumour agents, but dimeric ring-fused adducts are new. The alicyclic [1,2-a] ring-fused dimethoxybenzimidazole-benzimidazolequinone (DMBBQ) intermediate allows late-stage functionalization of bis-p-benzimidazolequinones. DMBBQs are chlorinated and brominated at the p-dimethoxybenzene site using nontoxic sodium halide and Oxone in HFIP/water.

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Correction for 'Visible-light unmasking of heterocyclic quinone methide radicals from alkoxyamines' by Patrick Kielty et al., Chem. Commun.

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In nature, the unmasking of heterocyclic quinones to form stabilized quinone methide radicals is achieved using reductases (bioreduction). Herein, an alternative controllable room-temperature, visible-light activated protocol using alkoxyamines and bis-alkoxyamines is provided. Selective synthetic modification of the bis-alkoxyamine, allowed chromophore deactivation to give one labile alkoxyamine moiety.

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