1-Dodecyl-2-methylpyridinium bromide ([C-2-Pic][Br]) and 1-hexadecyl-2-methylpyridinium bromide ([C-2-Pic][Br]) are two ionic liquid crystals presenting thermotropic smectic phases above 80 °C. Aiming to take advantage of the liquid crystalline properties at lower temperatures, lyotropic aqueous systems were prepared from these two organic salts. Both systems were characterized by polarized optical microscopy (POM), X-ray powder diffraction (XRD), and fast field cycling nuclear magnetic resonance (FFC-NMR) relaxometry to assess their texture, phase structure, and molecular dynamics, respectively.
View Article and Find Full Text PDFWater dynamics in mesoporous dextran hydrogel micro/nanoparticles was investigated by means of nuclear magnetic resonance (NMR) techniques. High-resolution H NMR spectra and pulsed field gradient (PFG) NMR diffusometry measurements obtained on swollen state dextran micro/nanogel revealed the existence of different fractions of water molecules based on their interaction with the gel matrix. In addition to the translational diffusion of bulk water, two more diffusion processes characterized with self-diffusion coefficients 1 and 2 orders of magnitude smaller than that of bulk water were identified.
View Article and Find Full Text PDFIndustrial inspection is crucial for maintaining quality and safety in industrial processes. Deep learning models have recently demonstrated promising results in such tasks. This paper proposes YOLOX-Ray, an efficient new deep learning architecture tailored for industrial inspection.
View Article and Find Full Text PDFSoil nutrients assessment has great importance in horticulture. Implementation of an information system for horticulture faces many challenges: (i) great spatial variability within farms (e.g.
View Article and Find Full Text PDFLocal molecular ordering in liquids has attracted a lot of interest from researchers investigating crystallization, but is still poorly understood on the molecular scale. Classical nucleation theory (CNT), a macroscopic thermodynamic description of condensation, has shortcomings when dealing with clusters consisting of tens of molecules. Cluster formation and local order fluctuations in liquid media are difficult to study due to the limited spatial resolution of electron- and photon-imaging methods.
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