Defect-Induced Orbital Polarization and Collapse of Orbital Order in Doped Vanadium Perovskites.

We explore mechanisms of orbital-order decay in the doped Mott insulators R_{1-x}(Sr,Ca)_{x}VO_{3} (R=Pr,Y,La) caused by charged (Sr,Ca) defects. Our unrestricted Hartree-Fock analysis focuses on the combined effect of random charged impurities and associated doped holes up to x=0.5.

Defects, Disorder, and Strong Electron Correlations in Orbital Degenerate, Doped Mott Insulators.

We elucidate the effects of defect disorder and e-e interaction on the spectral density of the defect states emerging in the Mott-Hubbard gap of doped transition-metal oxides, such as Y(1-x)Ca(x)VO(3). A soft gap of kinetic origin develops in the defect band and survives defect disorder for e-e interaction strengths comparable to the defect potential and hopping integral values above a doping dependent threshold; otherwise only a pseudogap persists. These two regimes naturally emerge in the statistical distribution of gaps among different defect realizations, which turns out to be of Weibull type.

Formation of fragment ions (H+, H3+, CH3+) from ethane in intense femtosecond laser fields--from understanding to control.

The dissociative ionization of ethane in intense femtosecond laser fields has been investigated as a function of the laser pulse shape by systematically varying the quadratic spectral phase, i.e. the linear chirp.

Hidden quasiparticles and incoherent photoemission spectra in Na2IrO3.

We study two Kitaev-Heisenberg t-J-like models on a honeycomb lattice, focusing on the zigzag magnetic phase of Na(2)IrO(3), and investigate hole motion by exact diagonalization and variational methods. The spectral functions are quite distinct from those of cuprates and are dominated by large incoherent spectral weight at high energy, almost independent of the microscopic parameters-a universal and generic feature for zigzag magnetic correlations. We explain why quasiparticles at low energy are strongly suppressed in the photoemission spectra and determine an analog of a pseudogap.

Analysis of chirality by femtosecond laser ionization mass spectrometry.

Recent progress in the field of chirality analysis employing laser ionization mass spectrometry is reviewed. Emphasis is given to femtosecond (fs) laser ionization work from the author's group. We begin by reviewing fundamental aspects of determining circular dichroism (CD) in fs-laser ionization mass spectrometry (fs-LIMS) discussing an example from the literature (resonant fs-LIMS of 3-methylcyclopentanone).