The authors wish to make the following corrections to this paper [1]: there are two mistakes inthis article [1] [...
View Article and Find Full Text PDFAn alternative route for metal hydrogenation has been investigated: cold plasma hydrogen implantation on polyol-made transition metal nanoparticles. This treatment applied to a challenging system, Ni-H, induces a re-ordering of the metal lattice, and superstructure lines have been observed by both Bragg-Brentano and grazing incidence X-ray diffraction. The resulting intermetallic structure is similar to those obtained by very high-pressure hydrogenation of nickel and prompt us to suggest that plasma-based hydrogen implantation in nanometals is likely to generate unusual metal hydride, opening new opportunities in chemisorption hydrogen storage.
View Article and Find Full Text PDFIn this work, we have investigated the structural, magnetic and magnetocaloric properties of LaCaMnO (A) and LaEuCaMnO (B) oxides. These compounds are synthesized by a solid-state reaction route and indexed with respect to SrTiO-type perovskite with the 4/ space group. The substitution of La by 10% Eu enhances the value of magnetization and reduces the Curie temperature ( ).
View Article and Find Full Text PDFThis review deals with the destabilization methods for improvement of storage properties of metal hydrides. Both theoretical and experimental approaches were used to point out the influence of various types of defects on structure and stability of hydrides. As a case study, Mg, and Ni based hydrides has been investigated.
View Article and Find Full Text PDFBoth numerical simulation and hardness measurements were used to determine the mechanical and microstructural behavior of AZ31 bulk samples when submitted to the Equal Channel Angular Pressing (ECAP) technique. Billets of this representative of Mg-rich alloys were submitted to different numbers of passes for various ECAP modes (anisotropic A, isotropic B). The strain distribution, the grain size refinement, and the micro-hardness were used as indicators to quantify the effectiveness of the different processing routes.
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