DNA origami nanostructures are emerging as a bottom-up nanopatterning approach. Direct combination of this approach with top-down nanotechnology, such as ion beams, has not been considered because of the soft nature of the DNA material. Here we demonstrate that the shape of 2D DNA origami nanostructures deposited on Si substrates is well preserved upon irradiation by ion beams, modeling ion implantation, lithography, and sputtering conditions.
View Article and Find Full Text PDFAs of early 2022, only six species bearing an N-O bond have been detected toward cold molecular clouds and regions of star formation. It is not clear yet if the small number of N-O bond species found in the interstellar medium so far stems from physical and technological limitations of astronomical detection techniques, or whether in fact molecules that bear an N-O bond are for some reason rare in these objects of the interstellar medium. Astronomical N-O bearing molecules are important because they are part of astrochemical models which propose that they are precursors of hydroxylamine (NHOH), a species linked to the formation of prebiotic amino acids in space.
View Article and Find Full Text PDFRadiolysis of biomolecules by fast ions has interest in medical applications and astrobiology. The radiolysis of solid D-valine (0.2-2 μm thick) was performed at room temperature by 1.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
March 2020
Several nitrogen-containing molecules have been unambiguously identified in the Solar System and in the Interstellar Medium. It is believed that such a rich inventory of species is a result of the energetic processing of astrophysical ices during the interaction with ionizing radiation. An intrinsic parameter of matter, the complex refractive index, stores all the "chemical memory" triggered by energetic processing, and therefore might be used to probe ice observations in the infrared.
View Article and Find Full Text PDFWater ice exists on many objects in space. The most abundant icy species, among them water, are present in the icy satellites of the outer Solar System giant planets. The nuclei of comets, which are mainly composed of water ice, give another example of its abundance.
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