Publications by authors named "P Bataillard"

While risk-based contaminated land management is an essential component of sustainable remediation, uncertainty is an unavoidable aspect of risk assessment, since most of the parameters that influence risk are typically affected by uncertainty. Uncertainty may be of different origins; i.e.

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Permanganate is an oxidant usually applied for in situ soil remediation due to its persistence underground. It has already shown great efficiency for dense nonaqueous phase liquid (DNAPL) degradation under batch experiment conditions. In the present study, experimental permanganate oxidation of a DNAPL - coal tar - sampled in the groundwater of a former coking plant was carried out in a glass bead column.

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Article Synopsis
  • In situ chemical oxidations effectively address PAH contaminations in groundwater and soils, with this study focusing on comparing three oxidation processes: permanganate, heat-activated persulfate, and Fenton-like reactions using magnetite against ferrates.
  • The research specifically highlights the limited effectiveness of Fenton-like processes for degradation, while heat-activated persulfate showed the best results without producing harmful oxygenated PAH by-products, and permanganate also performed well but generated significant amounts of ketones.
  • Ferrates, although efficient on various pollutants and yielding nontoxic by-products, exhibited lower degradation efficiency in soil applications and produced harmful oxygenated by-products, indicating a different reaction mechanism compared to the other tested oxidants.
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Two complementary approaches were used to characterize arsenic and metal mobilizations from a dredged-sediment disposal site: a detailed field study combined with hydrogeochemical modeling. Contaminants in sediments were found to be mainly present as sulfides subject to oxidation. Secondary phases (carbonates, sulfates, (hydr)oxides) were also observed.

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The management of dredged sediments is of environmental concern worldwide since they may be overloaded with myriads of pollutants. For inland waters' sediments, disposal on land is a common practice. For the long-term risks assessment of such a management, a better understanding of the fate of pollutants over time and an assessment of possible associated biological consequences are needed.

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