Occurrence and health risk estimate of organochlorine pesticides in fruits and vegetables matrices.

Occurrence of 20 organochlorine pesticides (OCPs) in 60 organic and non-organic fruits and vegetables matrices was undertaken using QuEChERS Method EN 15662 for sample preparation analyzed by gas chromatography-mass spectrometry (GC-MS/MS). The procedural method was validated by spiking the OCP standard solutions at three fortified levels at 10, 50, and 100 µg/kg wet weight (ww) to the real matrix of fruit and vegetable with good recovery ranging from 75 to 108% with relative standard deviation (RSD) ≤ 11%, and the limits of detection and quantification (LODs and LOQs) were 0.002-0.

Concentrations of bisphenols and phthalate esters in the muscle of Mediterranean striped dolphins (Stenella coeruleoalba).

Bisphenols (BPs) and phthalate esters (PAEs) are important compounds for the plastics industry, also called "everywhere chemicals" due to their ubiquity in daily use products. Both chemical groups are well-known environmental contaminants, whose presence has been reported in all environmental compartments, and whose effects, mainly associated to endocrine disruption, are detrimental to living organisms. Cetaceans, due to their long life-span, low reproduction rate and high position in the trophic web, are especially vulnerable to the effects of contaminants.

Trace metals exposure in three different coastal compartments show specific morphological and reproductive traits across generations in a sentinel copepod.

The effect of exposure from several compartments of the environment at the level of individuals was rarely investigated. This study reports the effect of contaminants from varied compartments like sediment resuspension, elutriation from resuspended sediment (extract) and seawater spiked trace metal mixtures (TM) on morphological and reproductive traits of the pelagic bioindicator copepod Eurytemora affinis. At the population level of E.

Bioaccumulation of trace metal elements and biomarker responses in caged juvenile flounder at a polluted site: Effects of fish density and time exposure.

This study investigates the effect of fish density and exposure duration on trace metal elements (TME) bioaccumulation and several biomarkers response. Juvenile flounders were caged at low, medium and high densities and exposed during 15 or 30 days in the Seine estuary. The concentrations of the TME measured in the muscle of the caged fish were all in agreement with their bioavailability percentage in the sediments.

Development of a TiO/Sepiolite Photocatalyst for the Degradation of a Persistent Organic Pollutant in Aqueous Solution.

A clay-based TiO nanocomposite material was synthesized by a facile method, to investigate its structure and photocatalytic efficiency. The supported TiO nanoparticles were generated using a sol-gel method, and subsequently, mixed with a suspension of sepiolite. The material was recovered in powder form (Mc-80) and then calcined to properly arrange the crystal lattice of the TiO particles for use in heterogeneous photocatalysis (Mc-80-500).

55 xenobiotic organic compounds in Tripoli landfill-Lebanon leachate and their fluxes to the Abou Ali River and Mediterranean Sea.

Pollution generated from landfill solid wastes constitute one of the major threat to the environment. The landfill leachate contains various toxic pollutants, making it the most dangerous issue of the landfills. Monitoring the xenobiotic organic concentrations in landfill leachate is an important step to evaluate the environmental impacts.

Responses of the copepod Eurytemora affinis to trace metal exposure: A candidate for sentinel to marine sediment resuspension effects.

Our study reports the ability of Eurytemora affinis to indicate certain responses in 96 h when exposed to resuspended sediment from a polluted site (PS, Seine estuary, France), less polluted site (LPS, Canche estuary, France) and dissolved trace metals. Mortality from dissolved trace metal was highest (57.5 %) followed by PS (38.

Impacts of chemical stress, season, and climate change on the flounder population of the highly anthropised Seine estuary (France).

The main objective of this study was to improve our knowledge on the responses of fish populations to multistress (diffuse pollution and warming waters) in estuaries. Adult flounders were caught in two estuaries in the Eastern English Channel: the heavily polluted Seine estuary vs the moderately contaminated Canche estuary. Fish samplings were conducted in January just before the reproduction period, and in July when gonads were at rest.

Intrapopulation and temporal differences of phthalate concentrations in North Atlantic fin whales (Balaenoptera physalus).

The fin whale (Balaenoptera physalus) is a migratory filter-feeding species that is susceptible to ingest plastics while lunge feeding across the oceans. Plastic additives, such as phthalates, are compounds that are added to plastics to give them specific characteristics, such as flexibility. These so-called plasticizers are currently raising major concern because of their potential adverse effects on marine fauna.

Multigenerational study of life history traits, bioaccumulation, and molecular responses of Pseudodiaptomus annandalei to cadmium.

Metal pollution provide a substantial challenge for environmental health. This study investigated the multigeneration effects of cadmium on populations of the copepod species Pseudodiaptomus annandalei, exposed to a sublethal concentration, 40 µg/L of cadmium (Cd), over 10 generations. At the end of each generation, copepod individuals were collected to estimate fecundity, bioaccumulation, and real time qPCR quantification of selected differentially expressed genes to evaluate Cd effects and sex-specific responses of copepods across multiple generations.

Single toxicity of arsenic and combined trace metal exposure to a microalga of ecological and commercial interest: Diacronema lutheri.

Eco-toxicological assays with species of economic interest such as Diacronema lutheri are essential for industries that produce aquaculture feed, natural food additives and also in drug developing industries. Our study involved the exposure of a single and combined toxicity of arsenic (As V) to D. lutheri for the entire algal growth phase and highlighted that a combined exposure of As V with other essential (Copper, Cu; Nickel, Ni) and non-essential (Cadmium, Cd; Lead, Pb) trace metals reduced significantly the cell number, chlorophyll a content, and also significantly increased the de-epoxidation ratio (DR) as a stress response when compared to the single toxicity of As V.

Elimination of organochlorine pesticides from water by a new activated carbon prepared from Phoenix dactylifera date stones.

This work focused on the characterization of activated carbon (AC) prepared by pyrolysis-chemical activation with phosphoric acid (60%) from date stones derived from three categories of date palm Phoenix dactylifera (Ajwa, Anbari, Khudri), and on its feasibility of elimination of organochlorine pesticides (OCPs) in water samples. The obtained results showed that the three-produced AC date stone had developed a porous structure, large specific surface area, and acidic property. Due to the high SBET (> 1200 m/g), Ajwa stones activated coal was considered as the best AC that can be used for the adsorption of environmental contaminants.

Simultaneous photocatalytic Cr(VI) reduction and phenol degradation over copper sulphide-reduced graphene oxide nanocomposite under visible light irradiation: Performance and reaction mechanism.

The contamination of water by synthetic organic molecules and trace metals is a growing challenge, in spite of the enormous research efforts being made in the field of water treatment. In this study, reduced graphene oxide-copper sulphide (rGO-CuS) nanocomposites of different rGO/CuS (2/1, 1/1, 1/2) molar ratios were fabricated via a facile one-step hydrothermal method. The nanocomposite materials, named hereafter as 2rGO-CuS, rGO-CuS and rGO-2CuS, were characterized using various analytical techniques, including X-ray diffraction (XRD), Raman spectroscopy, transmission electron microscopy (TEM), energy dispersive X-ray (EDX) spectroscopy, X-ray photoelectron spectroscopy (XPS) and UV-visible spectrophotometry.

Differential gene expression profile of male and female copepods in response to cadmium exposure.

In this study, the whole transcriptome and sex-specific differential gene expression of the copepod Pseudodiaptomus annandalei exposed to cadmium (Cd) were investigated. P. annandalei were exposed to 40 μg/L Cd from the naupliar stage to male and female adults.

Assessment of persistent organic pollutants in surface sediments along Lebanese coastal zone.

The levels of some persistent organic pollutants (POPs) along the Lebanese coastal zone (LCZ) were assessed by collecting15 surface sediments from five hotspot stations. Such stations were influenced by various industrial units, riverine input, and touristic activities. The levels of polycyclic aromatic hydrocarbons (∑16PAHs), their methylated derivatives (∑18Me-PAHs), and polychlorinated biphenyls (∑28PCBs) were in the range of 537-3773 μg∙kg dw, 187-1541 μg∙kg dw, and 143-303 μg∙kg dw respectively.

Effects of different routes of exposure to metals on bioaccumulation and population growth of the cyclopoid copepod Paracyclopina nana.

We examined effects of the three metals cadmium (Cd), copper (Cu), and nickel (Ni) on two subpopulations of the cyclopoid copepod Paracyclopina nana. We sought to investigate the effects of metal exposure on population growth and structure of P. nana and to understand the parameters affecting the metal bioaccumulation in copepods.

Formation and removal of disinfection by-products in a full scale drinking water treatment plant.

In this case study, high sensitivity simple methods for the analysis of trihalomethanes (THM4), iodinated-trihalomethanes (I-THMs), haloacetic acids (HAAs), bromide, iodide and iodate have been developed. A one-step procedure for the analysis of haloacetic acids by head-space GC-MS provides good reproducibility and low limits of quantification (≤50 ng L). These methods were applied to characterize the formation of disinfection by-products (DBPs) in a full scale drinking water treatment plant.

Coupling caging and proteomics on the European flounder (Platichthys flesus) to assess the estuarine water quality at micro scale.

Estuaries are important areas highly vulnerable to anthropogenic pollutions. Therefore, the assessment of estuarine water quality is a major ecological issue. In this study, we sampled juveniles of the European flounder in the "pristine" Canche estuary, and caged them in Canche and in two polluted sites of the Seine estuary, Rouen and Fosse Nord.

Bioaccumulation of metals in calanoid copepods by oral intake.

We demonstrated that oral intake of water by two calanoid copepods, Pseudodiaptomus annandalei and Eurytemora affinis takes place and has implications for their ecotoxicology. In the first experiment, copepods were exposed to a dyed medium, which allowed us to visually examine the possibility of water uptake by the copepod. We observed that both copepod species were taking in water orally and evacuated dye at different speeds.

Natural organic matter-cations complexation and its impact on water treatment: A critical review.

The quality and quantity of natural organic matter (NOM) has been observed to evolve which poses challenges to water treatment facilities. Even though NOM may not be toxic itself, its presence in water has aesthetic effects, enhances biological growth in distribution networks, binds with pollutants and controls the bioavailability of trace metals. Even though NOM has heterogeneous functional groups, the predominant ones are the carboxyl and the phenolic groups, which have high affinities for metals depending on the pH.

Population response of the estuarine copepod Eurytemora affinis to its bioaccumulation of trace metals.

We evaluated the acute toxicities of metals cadmium (Cd), copper (Cu) and nickel (Ni) to a widely-distributed copepod Eurytemora affinis isolated from the Seine estuary. Both sexes of adult E. affinis were exposed separately to the three metals at concentration gradients to determine its 50% lethal concentration (LC50).

PMS activation using reduced graphene oxide under sonication: Efficient metal-free catalytic system for the degradation of rhodamine B, bisphenol A, and tetracycline.

This study addresses the influence of ultrasound irradiation on the activation of peroxymonosulfate (PMS) using reduced graphene oxide (rGO) under metal-free conditions for the catalytic degradation of rhodamine B (RhB), bisphenol A (BPA) and tetracycline (TC). Our results revealed that the combination of PMS/rGO and ultrasonication enhanced significantly the degradation rate, reaching full degradation in relatively short times with total organic carbon (TOC) removal exceeding 85% of the investigated pollutants. In contrast, under these experimental conditions, rGO/ultrasound and PMS/ultrasound achieved less than 20% degradation of the same pollutants.

Assessment of trace metals contamination in surficial sediments along Lebanese Coastal Zone.

A Characterization and assessment study was conducted for trace metals pollution in surface sediments at six sites including harbors, bays and river input along Lebanese coast (LCZ). A particular attention was given to Tripoli Port in order to identify the main sources of trace metals pollution inside this harbor. Total metals concentrations were compared with those reported for the shale.