Use of a Glaciogene Marine Clay (Ilulissat, Greenland) in a Pilot Production of Red Bricks.

Uplifted occurrences of fine-grained glaciogene marine sediments are found throughout the northern hemisphere. These sediments could be used to produce local construction materials, to rely less on imported construction materials from southern regions. In this study, a representative occurrence from Ilulissat, West Greenland, was investigated as a potential resource for local brick production.

Bio-integrated carbon capture and utilization: at the interface between capture chemistry and archaeal CO reduction.

Carbon capture and utilization (CCU) covers an array of technologies for valorizing carbon dioxide (CO). To date, most mature CCU technology conducted with capture agents operates against the CO gradient to desorb CO from capture agents, exhibiting high energy penalties and thermal degradation due to the requirement for thermal swings. This Perspective presents a concept of Bio-Integrated Carbon Capture and Utilization (BICCU), which utilizes methanogens for integrated release and conversion of CO captured with capture agents.

Non-Destructive Testing for Documenting Properties of Structural Concrete for Reuse in New Buildings: A Review.

Reuse in new buildings of structural concrete components from demolitions holds the potential for avoiding the use of raw materials to produce new components, including cement for new castings. Reuse rates are high in the circular economy; however, reusing structural components requires documentation of the properties to equate the safety of using reused and new components. Yet, there is no structured or recognized way to perform the documentation.

Dewatering and valorizing lake sediments by electroosmotic dewatering for lakes restoration.

Dredging eutrophic lake sediments can improve water quality, but it also requires dewatering and valorizing the dredged material to avoid wasting resources like phosphorus. This study experimentally investigated the basic mechanism and performance of electroosmotic dewatering of 1-L dredged sediments using different electric currents (20 mA, 40 mA, and 60 mA) after gravity filtration. The dewatering performance, moisture content and distribution, effect of electrochemical reaction on dewaterability, energy consumption, and changes in metals and phosphorus (P) distribution and pH values were analyzed.

Heavy metal leaching from wood ash before and after hydration and carbonation.

Wood ashes can be used, e.g., as soil fertilizer or in construction materials; however, it is important to ensure that such use will not cause spreading of heavy metals and subsequent harm to the environment.

Continuous biomethanation of flue gas-carbon dioxide using bio-integrated carbon capture and utilization.

Biomethanation of carbon dioxide (CO) from flue gas is a potential enabler of the green transition, particularly when integrated with the power-to-gas chain. However, challenges arise in achieving synthetic natural gas quality when utilizing CO from diluted carbon sources, and the high costs of CO separation using amine-based solutions make large-scale implementation unfeasible. We propose an innovative continuous biomethanation system that integrates carbon capture and CO stripping through microbial utilization, eliminating expenses with the stripper.

Electrical current disrupts the electron transfer in defined consortia.

Improving methane production through electrical current application to anaerobic digesters has garnered interest in optimizing such microbial electrochemical technologies, with claims suggesting direct interspecies electron transfer (DIET) at the cathode enhances methane yield. However, previous studies with mixed microbial communities only reported interspecies interactions based on species co-occurrence at the cathode, lacking insight into how a poised cathode influences well-defined DIET-based partnerships. To address this, we investigated the impact of continuous and discontinuous exposure to a poised cathode (-0.

Recovery of Phosphorus and Metals from the Ash of Sewage Sludge, Municipal Solid Waste, or Wood Biomass: A Review and Proposals for Further Use.

This review provides an overview of methods to extract valuable resources from the ash fractions of sewage sludge, municipal solid waste, and wood biomass combustion. The resources addressed here include critical raw materials, such as phosphorus, base and precious metals, and rare earth elements for which it is increasingly important to tap into secondary sources in addition to the mining of primary raw materials. The extraction technologies prioritized in this review are based on recycled acids or excess renewable energy to achieve an optimum environmental profile for the extracted resources and provide benefits in the form of local industrial symbioses.

Phosphorous extraction and heavy metal separation from sewage sludge ash by two-compartment electrodialysis in an upscaled tube reactor.

Two-compartment electrodialytic extraction (2C-ED) is a one-step process for the simultaneous phosphorous extraction and separation of heavy metals from sewage sludge ash (SSA). The process is driven by an applied electric DC field, which can be supplied from renewable sources. The proof-of-concept of the method was conducted in small laboratory cells; however, upscaling to a continuous 2C-ED process, which additionally can treat SSA suspensions at a low liquid-to-solid (L:S) ratio, requires a new design.

Comparison of the photocatalytic degradability of PFOA, PFOS and GenX using Fe-zeolite in water.

Knowledge on the photocatalytic degradability of the emerging poly- and perfluorinated alkyl substances (PFAS) in water, specifically GenX, is limited. GenX has been detected globally in river water and is considered potentially more toxic than legacy PFAS. In this study, we compared the photocatalytic degradability of GenX with the legacy compounds perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) using Fe-zeolite photocatalysts.

Enhanced process control of trickle-bed reactors for biomethanation by vertical profiling directed by hydrogen microsensor monitoring.

Biomethanation is an emerging Power-to-X technology enabling CO valorisation to produce biomethane using renewable H. A promising reactor for facilitating biomethanation is the trickle bed reactor (TBR), however, these bioreactors are conventionally operated with a black-box approach, where the system is solely described by the input and output characteristics. This study employed a novel approach for process surveillance of internal dynamics in TBRs by installing multiple H microsensors along its vertical axis.

Complete defluorination of perfluorooctanoic acid (PFOA) by ultrasonic pyrolysis towards zero fluoro-pollution.

Advanced oxidation/reduction of PFAS is challenged and concerned by the formation of toxic, short-chain intermediates during water treatments. In this study, we investigated the complete defluorination of PFOA by ultrasound/persulfate (US/PS) with harmless end-products of CO, HO, and F ions. We observed 100% defluorination after 4 h of US treatment alone with a power input of 900 W.

Impacts of climate change on metal leaching and partitioning for submarine mine tailings disposal.

At present, there are no standardised tests to assess metal leaching during submarine tailings discharge. In this study the influence of variables known to affect metal mobility and availability (dissolved organic carbon (DOC), pH, salinity, temperature, aerated/anoxic conditions) along with variables affected by the discharge conditions (flocculant concentration, suspension) were studied in bench-scale experiments. The leaching tests were developed based on the case of a copper mine by Repparfjorden, northern Norway, which is planned to re-open in 2022.

Concentrate and degrade PFOA with a photo-regenerable composite of In-doped TNTs@AC.

"Concentrate-and-degrade" is an effective strategy to promote mass transfer and degradation of pollutants in photocatalytic systems, yet suitable and cost-effective photocatalysts are required to practice the new concept. In this study, we doped a post-transition metal of Indium (In) on a novel composite adsorptive photocatalyst, activated carbon-supported titanate nanotubes (TNTs@AC), to effectively degrade perfluorooctanoic acid (PFOA). In/TNTs@AC exhibited both excellent PFOA adsorption (>99% in 30 min) and photodegradation (>99% in 4 h) under optimal conditions (25 °C, pH 7, 1 atm, 1 g/L catalyst, 0.

Hydrodynamic analysis of full-scale in-situ biogas upgrading in manure digesters.

The addition of hydrogen to anaerobic digesters is an emerging technique for the sustainable upgrading of biogas to biomethane with renewable electricity. However, it is critically dependent on the effective gas-liquid transfer of hydrogen, which is a sparingly soluble gas. Very little is known about the impact of liquid and gas flow and bubble size on gas-liquid transfer during H injection in full-scale anaerobic digesters.

Cellulolytic and Xylanolytic Microbial Communities Associated With Lignocellulose-Rich Wheat Straw Degradation in Anaerobic Digestion.

The enzymatic hydrolysis of lignocellulosic polymers is generally considered the rate-limiting step to methane production in anaerobic digestion of lignocellulosic biomass. The present study aimed to investigate how the hydrolytic microbial communities of three different types of anaerobic digesters adapted to lignocellulose-rich wheat straw in continuous stirred tank reactors operated for 134 days. Cellulase and xylanase activities were monitored weekly using fluorescently-labeled model substrates and the enzymatic profiles were correlated with changes in microbial community compositions based on 16S rRNA gene amplicon sequencing to identify key species involved in lignocellulose degradation.

Recovering rare earth elements from contaminated soils: Critical overview of current remediation technologies.

Rare earth elements (REE) are essential for sustainable energies such as solar and wind power, with rising demand due to the ambitious goal for a circular society. REE are currently mined from virgin ores while REE-rich contaminated soil is left untreated in the environment. Soil remediation strategies are needed that concomitantly cleanup soil and harvest metals that contribute to process circular economy.

Transformation of tetrachloroethylene in a flow-through electrochemical reactor.

Electrochemical transformation of harmful tetrachloroethylene (PCE) is evaluated as a method for management of groundwater plumes to protect the drinking water resource, its consumers and the environment. In contrast to previous work that reported transformation of trichloroethylene, a byproduct of PCE, this work focuses on transformation of PCE in a saturated porous matrix and the influence of design parameters on the removal performance. Design parameters investigated were electrode configuration, catalyst load, electrode spacing, current intensity, orientation of reactor and flow through a porous matrix.

Electrochemical transformation of an aged tetrachloroethylene contamination in realistic aquifer settings.

Electrochemical removal of chlorinated ethenes in groundwater plumes may potentially overcome some of the challenges faced by current remediation technologies. So far, studies have been conducted in simplified settings of synthetic groundwater and inert porous matrices. This study is a stepwise investigation of the influence of field-extracted groundwater, sandy sediment and groundwater aquifer temperatures on the removal of an aged partially degraded contamination of tetrachloroethylene (PCE) at a typical groundwater flow rate.

Stick or leave - Pushing methanogens to biofilm formation for ex situ biomethanation.

Biomethanation exploits the ability of methanogenic archaea to convert CO and renewable H from electrolysis to biomethane. Biofilm reactors are promising for biomethanation scale-up due to high CH productivity and low energy input for H gas-liquid mass transfer. Effects of operational conditions on biofilm dynamics remain largely uncharacterized but may increase reactor potentials further.

Electrokinetics applied in remediation of subsurface soil contaminated with chlorinated ethenes - A review.

Electrokinetics is being applied in combination with common insituremediation technologies, e.g. permeable reactive barriers, bioremediation and in-situ chemical oxidation, to overcome experienced limitations in remediation of chlorinated ethenes in low-permeable subsurface soils.

Anammox and partial nitritation in the mainstream of a wastewater treatment plant in a temperate region (Denmark).

The Marselisborg WWTP (Aarhus, Denmark) fed the mainstream nitrification/denitrification tanks with excess sludge from a sidestream DEMON tank for more than three years to investigate if anammox can supplement conventional nitrification/denitrification in a mainstream of a temperate region. To evaluate this long-term attempt, anammox and also denitrification rates were measured in activated sludge from the main- and sidestream at 10, 20 and 30 °C using N-labelling (stable isotope) experiments. The results show that anammox contributes by approximately 1% of the total nitrogen removal in the mainstream tanks and that anammox conversion rates there are approximately 800-900 times lower than in the DEMON.

Biogas upgrading with hydrogenotrophic methanogenic biofilms.

Hydrogen produced from periodic excess of electrical energy may be added to biogas reactors where it is converted to CH that can be utilized in the existing energy grid. The major challenge with this technology is gas-to-liquid mass transfer limitation. The microbial conversions in reactors designed for hydrogenotrophic methanogenesis were studied with microsensors for H, pH, and CO.

How Low Can You Go: Methane Production of at Low CO Concentrations.

Autotrophic hydrogenotrophic methanogens use H/CO as sole carbon and energy source. In contrast to H, CO is present in high concentrations in environments dominated by methanogens e.g.